The renaissance of non‐aqueous uranium chemistry
ST Liddle - Angewandte Chemie International Edition, 2015 - Wiley Online Library
Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …
Thermal and Photochemical Reduction and Functionalization Chemistry of the Uranyl Dication, [UVIO2]2+
The uranyl ion,[UVIO2] 2+, possesses rigorously trans, strongly covalent, and chemically
robust U-oxo groups. However, through the use of anaerobic reaction techniques, both one …
robust U-oxo groups. However, through the use of anaerobic reaction techniques, both one …
Actinide-based single-molecule magnets
KR Meihaus, JR Long - Dalton Transactions, 2015 - pubs.rsc.org
Actinide single-molecule magnetism has experienced steady growth over the last five years
since the first discovery of slow magnetic relaxation in the mononuclear complex U …
since the first discovery of slow magnetic relaxation in the mononuclear complex U …
Quantitative Evidence for Lanthanide-Oxygen Orbital Mixing in CeO2, PrO2, and TbO2
Understanding the nature of covalent (band-like) vs ionic (atomic-like) electrons in metal
oxides continues to be at the forefront of research in the physical sciences. In particular, the …
oxides continues to be at the forefront of research in the physical sciences. In particular, the …
Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species
P Thuéry, J Harrowfield - Dalton Transactions, 2017 - pubs.rsc.org
An overview is given of recent structural studies on heterometallic uranyl-containing species,
with particular emphasis on those formed with carboxylate ligands, showing the effect of the …
with particular emphasis on those formed with carboxylate ligands, showing the effect of the …
Recent developments in metal dipyrrin complexes: Design, synthesis, and applications
This in-depth review covers recent developments in the area of metal dipyrrinato complexes
based on dipyrrins, a unique class of compounds which have fascinated the scientific …
based on dipyrrins, a unique class of compounds which have fascinated the scientific …
Organometallic neptunium chemistry
PL Arnold, MS Dutkiewicz, O Walter - Chemical Reviews, 2017 - ACS Publications
Fifty years have passed since the foundation of organometallic neptunium chemistry, and yet
only a handful of complexes have been reported, and even fewer have been fully …
only a handful of complexes have been reported, and even fewer have been fully …
Actinide-based single-molecule magnets: alone or in a group?
M Liu, XH Peng, FS Guo, ML Tong - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
In recent years, very significant progress has been made in single-molecule magnets
(SMMs), and one of the major milestone works is the hysteresis blocking temperature …
(SMMs), and one of the major milestone works is the hysteresis blocking temperature …
Direct observation of pure pentavalent uranium in U2O5 thin films by high resolution photoemission spectroscopy
Thin films of the elusive intermediate uranium oxide U2O5 have been prepared by exposing
UO3 precursor multilayers to atomic hydrogen. Electron photoemission spectra measured …
UO3 precursor multilayers to atomic hydrogen. Electron photoemission spectra measured …
Inner-sphere vs. outer-sphere reduction of uranyl supported by a redox-active, donor-expanded dipyrrin
JR Pankhurst, NL Bell, M Zegke, LN Platts… - Chemical …, 2017 - pubs.rsc.org
The uranyl (VI) complex UO2Cl (L) of the redox-active, acyclic diimino-dipyrrin anion, L− is
reported and its reaction with inner-and outer-sphere reductants studied. Voltammetric, EPR …
reported and its reaction with inner-and outer-sphere reductants studied. Voltammetric, EPR …