Hydrogen isotope separation in confined nanospaces: carbons, zeolites, metal–organic frameworks, and covalent organic frameworks

JY Kim, H Oh, HR Moon - Advanced Materials, 2019 - Wiley Online Library
One of the greatest challenges of modern separation technology is separating isotope
mixtures in high purity. The separation of hydrogen isotopes can create immense economic …

A mini-review of the current progress and future challenges of zeolites for hydrogen isotopes separation through a quantum effect

SH So, H Oh - International Journal of Hydrogen Energy, 2024 - Elsevier
Deuterium or tritium, which are rare isotopologues of hydrogen, are in high demand across
various industries; thus it is crucial to develop a separation technology for hydrogen …

Recent progress in functional nanomaterials towards the storage, separation, and removal of tritium

M Rethinasabapathy, SM Ghoreishian… - Advanced …, 2023 - Wiley Online Library
Tritium is a sustainable next‐generation prime fuel for generating nuclear energy through
fusion reactions to fulfill the increasing global energy demand. Owing to the scarcity–high …

Backscattering silicon spectrometer (BASIS): sixteen years in advanced materials characterization

NC Osti, N Jalarvo, E Mamontov - Materials Horizons, 2024 - pubs.rsc.org
Quasielastic neutron scattering (QENS) is an experimental technique that can measure
parameters of mobility, such as diffusion jump rate and jump length, as well as localized …

High-throughput computational exploration of MOFs with open Cu sites for adsorptive separation of hydrogen isotopes

Y Chen, X Bai, D Liu, X Fu, Q Yang - ACS Applied Materials & …, 2022 - ACS Publications
Effective separation of hydrogen isotopes still remains one of the extremely challenging
tasks in industry. Compared to the present methods that are energy-and cost-intensive …

Elucidation of Diffusivity of Hydrogen Isotopes in Flexible MOFs by Quasi‐Elastic Neutron Scattering

M Jung, J Park, R Muhammad, JY Kim… - Advanced …, 2021 - Wiley Online Library
Kinetic‐quantum‐sieving‐assisted H2: D2 separation in flexible porous materials is more
effective than the currently used energy‐intensive cryogenic distillation and girdle‐sulfide …

Highly effective hydrogen isotope separation through dihydrogen bond on Cu (I)-exchanged zeolites well above liquid nitrogen temperature

R **ong, L Zhang, P Li, W Luo, T Tang, B Ao… - Chemical Engineering …, 2020 - Elsevier
Hydrogen isotope separation under moderate conditions with high selectivity remains a
huge challenge due to the identical physicochemical properties of the isotopes. Here, we …

Thermodynamics, kinetics and selectivity of H2 and D2 on zeolite 5A below 77K

R **ong, RB **cohténcatl, L Zhang, P Li, Y Yao… - Microporous and …, 2018 - Elsevier
Thermodynamics, kinetics and selectivity of H 2 and D 2 on zeolite 5A have been
investigated by isotherm adsorption/desorption and thermal desorption spectroscopy (TDS) …

Hydrogen densification in carbon nanopore confinement: Insights from small-angle neutron scattering using a hierarchical contrast model

S Stock, M Seyffertitz, N Kostoglou, MV Rauscher… - Carbon, 2024 - Elsevier
This study reports on the low-pressure hydrogen (H 2) and deuterium (D 2) physisorption
processes in nanoporous activated carbon cloth at supercritical temperatures. In-situ small …

Ultrahigh effective H 2/D 2 separation in an ultramicroporous metal–organic framework material through quantum sieving

D Cao, H Huang, Y Lan, X Chen, Q Yang… - Journal of Materials …, 2018 - pubs.rsc.org
An ultramicroporous MOF material,{[Fe (OH)(H2bta)](H2O)} n, was diligently selected for the
experimental investigations of ultralow-temperature separation of H2/D2 through quantum …