Chemical principles of single-molecule electronics

TA Su, M Neupane, ML Steigerwald… - Nature Reviews …, 2016 - nature.com
The field of single-molecule electronics harnesses expertise from engineering, physics and
chemistry to realize circuit elements at the limit of miniaturization; it is a subfield of …

Silane and germane molecular electronics

TA Su, H Li, RS Klausen, NT Kim… - Accounts of Chemical …, 2017 - ACS Publications
Conspectus This Account provides an overview of our recent efforts to uncover the
fundamental charge transport properties of Si–Si and Ge–Ge single bonds and introduce …

Controllable Si− C bond activation enables stereocontrol in the palladium‐catalyzed [4+ 2] annulation of cyclopropenes with benzosilacyclobutanes

XB Wang, ZJ Zheng, JL **e, XW Gu… - Angewandte Chemie …, 2020 - Wiley Online Library
A novel and unusual palladium‐catalyzed [4+ 2] annulation of cyclopropenes with
benzosilacyclobutanes is reported. This reaction occurred through chemoselective Si− C …

Spatial variation of a giant spin–orbit effect induces electron confinement in graphene on Pb islands

F Calleja, H Ochoa, M Garnica, S Barja, JJ Navarro… - Nature Physics, 2015 - nature.com
The electronic band structure of a material can acquire interesting topological properties in
the presence of a magnetic field or as a result of the spin–orbit coupling,,. We study …

Promising anchoring groups for single-molecule conductance measurements

V Kaliginedi, AV Rudnev, P Moreno-García… - Physical Chemistry …, 2014 - pubs.rsc.org
The understanding of the charge transport through single molecule junctions is a
prerequisite for the design and building of electronic circuits based on single molecule …

Synthesis of silacyclobutanes and their catalytic transformations enabled by transition-metal complexes

QC Mu, J Chen, CG **a, LW Xu - Coordination Chemistry Reviews, 2018 - Elsevier
Silacyclobutanes (SCB), a family of useful organosilicon compounds, have attracted much
attention because the highly strained silicon-carbon bond can be activated, as evidenced by …

Using automated synthesis to understand the role of side chains on molecular charge transport

S Li, ER Jira, NH Angello, J Li, H Yu, JS Moore… - Nature …, 2022 - nature.com
The development of next-generation organic electronic materials critically relies on
understanding structure-function relationships in conjugated polymers. However, unlocking …

Chiral Single‐Molecule Potentiometers Based on Stapled ortho‐ Oligo(phenylene)ethynylenes

AM Ortuño, P Reiné… - Angewandte Chemie …, 2023 - Wiley Online Library
We report on the chemical design of chiral molecular junctions with stress‐dependent
conductance, whose helicity is maintained during the stretching of a single molecule …

An SN1-Approach to Cross-Coupling: Deoxygenative Arylation Facilitated by the β-Silicon Effect

A Cook, A Kassymbek, A Vaezghaemi… - Journal of the …, 2024 - ACS Publications
We report a dual metal-catalyzed method for the cross-coupling of unprotected alcohols by
exploiting the β-Si effect. This deoxygenative Suzuki-Miyaura reaction tolerates a range of …

Synthesis of alternating donor–acceptor ladder‐type molecules and investigation of their multiple charge‐transfer pathways

Z Cai, N Zhang, MA Awais, AS Filatov… - Angewandte …, 2018 - Wiley Online Library
We describe the synthesis as well as the optical and charge‐transport properties of a series
of donor–acceptor (D‐A) ladder‐type heteroacenes. These molecules are stable, soluble …