Emerging progress: photochemical transformation of nitroso compounds

ZL Chen, QQ Li, A Studer, J Xuan - Science China Chemistry, 2025 - Springer
Nitroso compounds have emerged as highly valuable reaction partners or reagents in
organic synthesis due to their rich reactivity. The versatile profile of these compounds allows …

Reprint of: Recent advances in the functionalization of allenes via radical process

G Qiu, J Zhang, K Zhou, J Wu - Tetrahedron, 2019 - Elsevier
This review is focused on the recent advances in the functionalization of allenes via radical
process. Different radical partners including carbon radicals and heteroatom radicals are …

Trifunctionalization of alkenes and alkynes

S Ghosh, D Lai, A Hajra - Organic & Biomolecular Chemistry, 2020 - pubs.rsc.org
Trifunctionalization is a versatile procedure to enable complex and diverse chemical
compounds by constructing three functional groups concurrently in one step from simple and …

Gold (I)-catalyzed highly enantioselective [4+ 2]-annulations of cyclopentadienes with nitrosoarenes via nitroso-Povarov versus oxidative nitroso-Povarov reactions

PD Jadhav, JX Chen, RS Liu - ACS Catalysis, 2020 - ACS Publications
This work reports gold-catalyzed highly enantioselective nitroso-Povarov reactions between
cyclopentadienes and nitrosoarenes in cold dichloroethane, in which nitrosoarenes serve as …

Gold‐catalyzed [4+ 2] Annulations of Dienes with Nitrosoarenes as 4 π Donors: Nitroso‐Povarov Reactions

CN Chen, RS Liu - Angewandte Chemie, 2019 - Wiley Online Library
This work reports the first success of the nitroso‐Povarov reaction, involving gold‐catalyzed
[4+ 2] annulations of nitrsoarenes with substituted cyclopentadienes. In this catalytic …

Nitrosoarenes implement cascade cyclization of 1-Allenyl-2-alkynylbenzenes through diradical mechanism

C Maitra, PD Jadhav, D Barik, YS Ho, CC Cheng… - Organic …, 2022 - ACS Publications
This work reports cascade cyclization between 1-allenyl-2-alkynylbenzenes and
nitrosoarenes. When these two components reacted alone under N2, N, O-functionalized …

Radical chemistry of nitrosoarenes: Concepts, synthetic applications and directions

Y Gao, S Yang, W **
RM Ward, JM Schomaker - The Journal of organic chemistry, 2021 - ACS Publications
Radical-mediated trifunctionalizations of allenes are virtually unknown, in contrast to well-
studied radical difunctionalizations of alkenes and alkynes. In this article, we describe a light …