Since the last century, we have witnessed the development of molecular magnetism which
deals with magnetic materials based on molecular species, ie, organic radicals and metal …

The development of molecular materials whose physical properties can be controlled by
external stimuli—such as light, electric field, temperature, and pressure—has recently …

Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

The study of paramagnetic compounds based on 4d and 5d transition metals is an emerging
research topic in the field of molecular magnetism. An essential driving force for the interest …

Metal‐to‐metal charge transfer (MMCT) describes electron transfer between metal ions, to
generate valence isomers with markedly different electronic configurations. In particular …

The study of photoinduced phase-transition materials has implications for the fields of
inorganic chemistry, solid-state chemistry, and materials science. Cyano-bridged bimetal …

A series of cyanide bridged Fe− Co molecular squares,[Co2Fe2 (CN) 6 (tp*) 2 (dtbbpy)
4](PF6) 2· 2MeOH (1),[Co2Fe2 (CN) 6 (tp*) 2 (bpy) 4](PF6) 2· 2MeOH (2), and [Co2Fe2 (CN) …

The coordination chemistry of transition metal hexacyanometallates is a field of continuous
advances and emerging applications. In the last three decades, relevant progress has been …

Cyano-bridged bimetal assemblies demonstrate novel magnetic functionalities, particularly
Prussian blue analogs, which have unique properties. In this perspective, we describe a …

Colossal and anisotropic thermal expansion is a key function for microscale or nanoscale
actuators in material science. Herein, we present a hexanuclear compound of [(Tp*) FeIII …