Homogeneous catalysis of dioxygen reduction by molecular Mn complexes
Continually increasing global energy demand perpetuates the need for effective alternative
energy sources and 'green'industrial processes. The oxygen reduction reaction (ORR) is …
energy sources and 'green'industrial processes. The oxygen reduction reaction (ORR) is …
Isolating Fe-O2 Intermediates in Dioxygen Activation by Iron Porphyrin Complexes
X Lu, S Wang, JH Qin - Molecules, 2022 - mdpi.com
Dioxygen (O2) is an environmentally benign and abundant oxidant whose utilization is of
great interest in the design of bioinspired synthetic catalytic oxidation systems to reduce …
great interest in the design of bioinspired synthetic catalytic oxidation systems to reduce …
Hydroxyl Transfer to Carbon Radicals by Mn (OH) vs Fe (OH) Corrole Complexes
DC Cummins, JG Alvarado, JPT Zaragoza… - Inorganic …, 2020 - ACS Publications
The transfer of• OH from metal-hydroxo species to carbon radicals (R•) to give hydroxylated
products (ROH) is a fundamental process in metal-mediated heme and nonheme C–H bond …
products (ROH) is a fundamental process in metal-mediated heme and nonheme C–H bond …
Controlling product selectivity during dioxygen reduction with Mn complexes using pendent proton donor relays and added base
The catalytic reduction of dioxygen (O2) is important in biological energy conversion and
alternative energy applications. In comparison to Fe-and Co-based systems, examples of …
alternative energy applications. In comparison to Fe-and Co-based systems, examples of …
Selective oxygenation of C–H and C [double bond, length as m-dash] C bonds with H 2 O 2 by high-spin cobalt (ii)-carboxylate complexes
Four cobalt (II)–carboxylate complexes [(6-Me3-TPA) CoII (benzoate)](BPh4)(1),[(6-Me3-
TPA) CoII (benzilate)](ClO4)(2),[(6-Me3-TPA) CoII (mandelate)](BPh4)(3), and [(6-Me3-TPA) …
TPA) CoII (benzilate)](ClO4)(2),[(6-Me3-TPA) CoII (mandelate)](BPh4)(3), and [(6-Me3-TPA) …
Photocatalytic generation of a non-heme Fe (iii)-hydroperoxo species with O 2 in water for the oxygen atom transfer reaction
E Pugliese, NT Vo, A Boussac, F Banse… - Chemical …, 2022 - pubs.rsc.org
Coupling a photoredox module and a bio-inspired non-heme model to activate O2 for the
oxygen atom transfer (OAT) reaction requires a vigorous investigation to shed light on the …
oxygen atom transfer (OAT) reaction requires a vigorous investigation to shed light on the …
Oxidation of an indole substrate by porphyrin iron (iii) superoxide: relevance to indoleamine and tryptophan 2, 3-dioxygenases
Reaction of FeIII (O2˙−)(TPP) with 2, 3-dimethylindole at− 40° C gives the ring-opened,
dioxygenated N-(2-acetyl-phenyl)-acetamide product. The reaction was monitored in situ by …
dioxygenated N-(2-acetyl-phenyl)-acetamide product. The reaction was monitored in situ by …
Oxygen versus Sulfur Coordination in Cobalt Superoxo Complexes: Spectroscopic Properties, O2 Binding, and H-Atom Abstraction Reactivity
A five-coordinate, disiloxide-ligated cobalt (II)(S= 3/2) complex (1) was prepared as an
oxygen-ligated analogue to the previously reported silanedithiolate-ligated CoII …
oxygen-ligated analogue to the previously reported silanedithiolate-ligated CoII …
Iron Porphyrin as a Cytochrome P450 Model for the Degradation of Dye
Organic dyes are widely used in the textile, biological, medical and other fields. However, a
serious environmental problem has appeared because of the presence of organic dyes in …
serious environmental problem has appeared because of the presence of organic dyes in …
Synthetic biology and healthcare
D Tew - Emerging Topics in Life Sciences, 2019 - portlandpress.com
Through the application of the engineering paradigm of 'design–build–test–learn'allied to
recent advances in DNA sequencing, bioinformatics and, critically, the falling cost of DNA …
recent advances in DNA sequencing, bioinformatics and, critically, the falling cost of DNA …