The Pd‐catalyzed coupling of aryl (pseudo) halides and amines is one of the most powerful
approaches for the formation of C (sp2)− N bonds. The pioneering reports from Migita and …

Many chemical reactions contain heterogeneous reagents, products, byproducts, or
catalysts, making their transposition from batch to continuous-flow processing challenging …

The palladium-catalyzed cross-coupling of amines and aryl (pseudo) halides, now
commonly known as the Buchwald–Hartwig amination, was first reported 25 years ago …

Oscillatory flow reactors (OFRs) superimpose an oscillatory flow to the net movement
through a flow reactor. OFRs have been engineered to enable improved mixing, excellent …

Continuous stirred tank reactors (CSTRs) facilitate chemical manufacture in continuous flow
and have been used for decades. They excel at solid handling and have well understood …

Carbon nitride materials have emerged as an efficient and sustainable class of
heterogeneous photocatalysts, particularly when paired with nickel in dual catalytic cross …

While ligand-enabled metal-catalyzed cross-coupling has emerged as a versatile approach
to thermal C (sp2)–O bond formation, broadly effective catalysts capable of employing a …

Despite the very simple geometry, T-shaped micro-mixers are characterized by different flow
regimes when operated for liquid mixing. In this work, experiments and direct numerical …

This review is a critical presentation of catalysts based on palladium and ruthenium bearing
N-heterocyclic carbene ligands that have enabled a more sustainable approach to catalysis …

Recent advances in Pd-catalyzed carbon–nitrogen cross-coupling have enabled the use of
soluble organic bases instead of insoluble or strong inorganic bases that are traditionally …