The amide bond represents the most fundamental functional group in numerous areas of
chemistry, such as organic synthesis, drug discovery, polymers, and biochemistry. Although …

The field of multimetallic catalysis is rapidly develo** and some multimetallic complexes
catalyze organic transformations to yield the desired products in more efficient ways owing …

The transition metal catalyzed amide bond forming reaction of esters with amines has been
developed as an advanced approach for overcoming the shortcomings of traditional …

Amide C− N bonds are thermodynamically stable and their fission, such as by hydrolysis
and alcoholysis, is considered a long‐challenging organic reaction. In general …

Direct functionalization of the C (O)–N amide bond is one of the most high-profile research
directions in the last few decades; however oxidative couplings involving amide bonds and …

Hydrolysis of amides to carboxylic acids is an industrially important reaction but is
challenging due to the difficulty of cleaving the resonance stabilized amidic C–N bond …

A novel approach for the efficient cleavage of the amide bonds in tertiary amides is reported.
Based on the selective radical abstraction of a benzylic hydrogen atom by a …

Preparation of catalytically active dinuclear transition metal complexes with an open
coordination sphere is a challenging task because the metal sites tend to be “saturated” with …

A straightforward TMSCF3‐catalyzed conversion of Weinreb amides into esters through the
treatment with sodium alkoxides is reported. The procedure documents a genuine selectivity …

Activated primary, secondary, and tertiary amides were coupled with enolizable esters in the
presence of LiHMDS to obtain good yields of β-ketoesters at room temperature. Notably, this …