A historical overview of the activation and porosity of metal–organic frameworks
Since the first reports of metal–organic frameworks (MOFs), this unique class of crystalline,
porous materials has garnered increasing attention in a wide variety of applications such as …
porous materials has garnered increasing attention in a wide variety of applications such as …
Metal–organic frameworks based on multicarboxylate linkers
When designing metal–organic frameworks (MOFs), linker design is one of the most
important factors in constructing a wide variety of structures. Judicious choice of linker size …
important factors in constructing a wide variety of structures. Judicious choice of linker size …
Sha** the water-harvesting behavior of metal–organic frameworks aided by fine-tuned GPT models
We construct a data set of metal–organic framework (MOF) linkers and employ a fine-tuned
GPT assistant to propose MOF linker designs by mutating and modifying the existing linker …
GPT assistant to propose MOF linker designs by mutating and modifying the existing linker …
Design and applications of water-stable metal-organic frameworks: status and challenges
Metal-organic frameworks (MOFs) have attracted broad interest of researchers in different
fields thanks to their high crystallinity, tunable porosity and chemical functionality. The …
fields thanks to their high crystallinity, tunable porosity and chemical functionality. The …
Overcoming the crystallization and designability issues in the ultrastable zirconium phosphonate framework system
Metal-organic frameworks (MOFs) based on zirconium phosphonates exhibit superior
chemical stability suitable for applications under harsh conditions. These compounds mostly …
chemical stability suitable for applications under harsh conditions. These compounds mostly …
Optimization of the pore structures of MOFs for record high hydrogen volumetric working capacity
Metal–organic frameworks (MOFs) are promising materials for onboard hydrogen storage
thanks to the tunable pore size, pore volume, and pore geometry. In consideration of pore …
thanks to the tunable pore size, pore volume, and pore geometry. In consideration of pore …
Single-Site Cobalt Catalysts at New Zr12(μ3-O)8(μ3-OH)8(μ2-OH)6 Metal–Organic Framework Nodes for Highly Active Hydrogenation of Nitroarenes, Nitriles …
We report here the synthesis of a robust and porous metal–organic framework (MOF), Zr12-
TPDC, constructed from triphenyldicarboxylic acid (H2TPDC) and an unprecedented Zr12 …
TPDC, constructed from triphenyldicarboxylic acid (H2TPDC) and an unprecedented Zr12 …
Controlled exchange of achiral linkers with chiral linkers in Zr-based UiO-68 metal–organic framework
C Tan, X Han, Z Li, Y Liu, Y Cui - Journal of the American …, 2018 - ACS Publications
The development of highly robust heterogeneous catalysts for broad asymmetric reactions
has always been a subject of interest, but it remains a synthetic challenge. Here we …
has always been a subject of interest, but it remains a synthetic challenge. Here we …
Topology-based functionalization of robust chiral Zr-based metal–organic frameworks for catalytic enantioselective hydrogenation
The design and development of robust and porous supported catalysts with high activity and
selectivity is extremely significant but very challenging for eco-friendly synthesis of fine …
selectivity is extremely significant but very challenging for eco-friendly synthesis of fine …
Single-Site Cobalt Catalysts at New Zr8(μ2-O)8(μ2-OH)4 Metal-Organic Framework Nodes for Highly Active Hydrogenation of Alkenes, Imines, Carbonyls, and …
We report here the synthesis of robust and porous metal–organic frameworks (MOFs), M-
MTBC (M= Zr or Hf), constructed from the tetrahedral linker methane-tetrakis (p …
MTBC (M= Zr or Hf), constructed from the tetrahedral linker methane-tetrakis (p …