Luminescent radicals
A Mizuno, R Matsuoka, T Mibu, T Kusamoto - Chemical Reviews, 2024 - ACS Publications
Organic radicals are attracting increasing interest as a new class of molecular emitters. They
demonstrate electronic excitation and relaxation dynamics based on their doublet or higher …
demonstrate electronic excitation and relaxation dynamics based on their doublet or higher …
Neutral d8 metal bis-dithiolene complexes: Synthesis, electronic properties and applications
B Garreau-de Bonneval, KIMC Ching, F Alary… - Coordination Chemistry …, 2010 - Elsevier
Transition metal bis-dithiolene complexes show a large variety of physical properties such
as conductivity, magnetism, optics, which render them attractive for new generations of …
as conductivity, magnetism, optics, which render them attractive for new generations of …
Hydrogen bond-promoted metallic state in a purely organic single-component conductor under pressure
T Isono, H Kamo, A Ueda, K Takahashi… - Nature …, 2013 - nature.com
Purely organic materials are generally insulating. Some charge-carrier generation, however,
can provide them with electrical conductivity. In multi-component organic systems, carrier …
can provide them with electrical conductivity. In multi-component organic systems, carrier …
Modern history of organic conductors: An overview
T Naito - Crystals, 2021 - mdpi.com
This short review article provides the reader with a summary of the history of organic
conductors. To retain a neutral and objective point of view regarding the history …
conductors. To retain a neutral and objective point of view regarding the history …
Zero-, one-and two-dimensional bis (dithiolato) metal complexes with unique physical and chemical properties
T Kusamoto, H Nishihara - Coordination Chemistry Reviews, 2019 - Elsevier
Bis (dithiolato) metal complexes, MDT2s, with π-conjugated molecular skeletons exhibit
multi-step ligand-centered or metal-centered redox activity and catalytic hydrogen evolution …
multi-step ligand-centered or metal-centered redox activity and catalytic hydrogen evolution …
A single-component molecular superconductor
HB Cui, H Kobayashi, S Ishibashi, M Sasa… - Journal of the …, 2014 - ACS Publications
The pressure dependence of the resistivities of a single-component molecular conductor,[Ni
(hfdt) 2](hfdt= bis (trifluoromethyl) tetrathiafulvalenedithiolate) with semiconducting …
(hfdt) 2](hfdt= bis (trifluoromethyl) tetrathiafulvalenedithiolate) with semiconducting …
Stable metallic state of a neutral-radical single-component conductor at ambient pressure
Y Le Gal, T Roisnel, P Auban-Senzier… - Journal of the …, 2018 - ACS Publications
Molecular metals have been essentially obtained with tetrathiafulvalene (TTF)-based
precursors, either with multicomponent ionic materials or, in a few instances, with single …
precursors, either with multicomponent ionic materials or, in a few instances, with single …
Mixed-ligand, radical, gold bis (dithiolene) complexes: from single-component conductors to controllable NIR-II absorbers
H Kharraz, P Alemany, E Canadell, Y Le Gal… - Chemical …, 2024 - pubs.rsc.org
Neutral radical bis (dithiolene) gold complexes [Au (dt) 2]˙ are known to exhibit a strong
absorption in the 1400–2000 nm NIR absorption range. Here, we demonstrate that the NIR …
absorption in the 1400–2000 nm NIR absorption range. Here, we demonstrate that the NIR …
Single-component molecular conductor [Pt (dmdt) 2]—A three-dimensional ambient-pressure molecular Dirac electron system
B Zhou, S Ishibashi, T Ishii, T Sekine… - Chemical …, 2019 - pubs.rsc.org
The single-component molecular conductor [Pt (dmdt) 2] is a sought-after ambient-pressure
molecular Dirac electron system, which exhibits a high temperature-insensitive conductivity …
molecular Dirac electron system, which exhibits a high temperature-insensitive conductivity …
Anisotropic chemical pressure effects in single-component molecular metals based on radical dithiolene and diselenolene gold complexes
G Yzambart, N Bellec, G Nasser… - Journal of the …, 2012 - ACS Publications
On the basis of the reported radical neutral complex [Au (Et-thiazdt) 2](Et-thiazdt= N-ethyl-1,
3-thiazoline-2-thione-4, 5-dithiolate), a series of single-component conductors derived from …
3-thiazoline-2-thione-4, 5-dithiolate), a series of single-component conductors derived from …