The use of transition‐metal complexes as homogeneous catalysts for the production of
organic chemicals is of considerable industrial significance. Although palladium complexes …

A survey of the chemistry of pentafulvene complexes of group four metals is presented.
Different synthetic procedures are discussed, leading to mono-and bis (η 5: η 1 …

We report the synthesis of the first early-lateheterobimetallic bridging imido complex Cp2Zr
(MNi-Bu)-IrCp*(1). Complex 1 was synthesized in 65% yield by the sequential addition of n …

Reactive monomeric amido and methoxo complexes, Cp* Ni (PEt3) NHTol and Cp* Ni
(PEt3) OMe, have been synthesized and fully characterized. The former is the first …

A series of palladium (II) radical carbene complexes,[PC˙(sp2) P] PdI,[PC˙(sp2) P] PdBr, and
[PC˙(sp2) P] PdCl (PC (sp3) H2P= bis [2-(di-iso-propylphosphino)-phenyl] methane), is …

The use of cyclopentadienyl ligands in organometallic chemistry and catalysis is ubiquitous,
mostly due to their robust spectator role. Nonetheless, increasing examples of non‐innocent …

The structures of neutral and ionic 4-cyanophenylpalladium (II) and methylpalladium (II)
complexes containing bidentate phosphine ligands were investigated in solution and in the …

An X-ray structure determination of III to verify both relative position and the bonding
situation of the methylene groups is hampered by disorder problems. Conformationof the …

The series of bis (pentafulvene) titanium complexes (η6-C5H4 CR2) 2Ti (CR2= C (p-tol) 2
(3), adamantyl (4)) and their corresponding bis (benzofulvene) derivatives (η6-C9H6 CR2) …

The crystal structure of TlC 5 Me 5 (I), obtained from Tl 2 SO 4 and NaC 5 Me 5, has been
determined. I crystallizes in the space group Pc (Z= 2) with a 1086 (1), b 1089 (1), c 1458 (1) …