Two-coordinate thermally activated delayed fluorescence coinage metal complexes: molecular design, photophysical characters, and device application

TY Li, SJ Zheng, PI Djurovich, ME Thompson - Chemical Reviews, 2024 - ACS Publications
Since the emergence of the first green light emission from a fluorescent thin-film organic light
emitting diode (OLED) in the mid-1980s, a global consumer market for OLED displays has …

Luminescent Complexes of Platinum, Iridium, and Coinage Metals Containing N-Heterocyclic Carbene Ligands: Design, Structural Diversity, and Photophysical …

H Amouri - Chemical Reviews, 2022 - ACS Publications
The employment of N-heterocyclic carbenes (NHCs) to design luminescent metal
compounds has been the focus of recent intense investigations because of the strong σ …

Cyclic (alkyl)-and (aryl)-(amino) carbene coinage metal complexes and their applications

R Jazzar, M Soleilhavoup, G Bertrand - Chemical Reviews, 2020 - ACS Publications
Cyclic (alkyl)-and (aryl)-(amino) carbenes (CAACs and CAArCs) are stronger σ-donors and
π-acceptors than imidazol-2-ylidenes and imidazolidin-2-ylidenes, the well-known N …

The golden age of thermally activated delayed fluorescence materials: design and exploitation

JM Dos Santos, D Hall, B Basumatary… - Chemical …, 2024 - ACS Publications
Since the seminal report by Adachi and co-workers in 2012, there has been a veritable
explosion of interest in the design of thermally activated delayed fluorescence (TADF) …

π-Extended ligands in two-coordinate coinage metal complexes

CN Muniz, J Schaab, A Razgoniaev… - Journal of the …, 2022 - ACS Publications
Two-coordinate carbene-MI-amide (cMa, MI= Cu, Ag, Au) complexes have emerged as
highly efficient luminescent materials for use in a variety of photonic applications due to their …

Charge-transfer processes in metal complexes enable luminescence and memory functions

VWW Yam, AKW Chan, EYH Hong - Nature Reviews Chemistry, 2020 - nature.com
Molecular transition-metal–ligand complexes are emerging as useful paradigms in materials
science. Transition metal complexes have diverse metal d electron configurations, oxidation …

Deep‐Blue and Fast Delayed Fluorescence from Carbene–Metal–Amides for Highly Efficient and Stable Organic Light‐Emitting Diodes

AC Brannan, HH Cho, APM Reponen… - Advanced …, 2024 - Wiley Online Library
Linear gold complexes of the “carbene–metal–amide”(CMA) type are prepared with a rigid
benzoguanidine amide donor and various carbene ligands. These complexes emit in the …

Au⋅⋅⋅ H− C Interactions Support a Robust Thermally Activated Delayed Fluorescence (TADF) Gold (I) Complex for OLEDs with Little Efficiency Roll‐Off and Good …

X Feng, JG Yang, J Miao, C Zhong, X Yin… - Angewandte …, 2022 - Wiley Online Library
The practical use of luminescent mononuclear gold (I) complexes as optoelectronic
materials has been limited by their inferior stability. Herein we demonstrate a strategy to …

LNL-Carbazole Pincer Ligand: More than the Sum of Its Parts

G Kleinhans, AJ Karhu, H Boddaert, S Tanweer… - Chemical …, 2023 - ACS Publications
The utility of carbazole in photo-, electro-, and medicinal applications has ensured its
widespread use also as the backbone in tridentate pincer ligands. In this review, the aim is …

Aggregation‐Dependent Circularly Polarized Luminescence and Thermally Activated Delayed Fluorescence from Chiral Carbene‐CuI‐Amide Enantiomers

A Ying, Y Ai, C Yang, S Gong - … Chemie International Edition, 2022 - Wiley Online Library
The field of luminescent carbene‐metal‐amide (CMA) complexes and chiroptical‐active
materials has been blossoming in recent years, although chiroptical‐active CMA complexes …