Mechanism of Co liner as enhancement layer for Cu interconnect gap-fill

M He, X Zhang, T Nogami, X Lin, J Kelly… - Journal of The …, 2013 - iopscience.iop.org
Cu gap-fill is enhanced by replacing the conventional Ta liner with a Co liner in a 22 nm
width interconnect structure. The improvement with Co liner seen at the line-end area is …

Galvanostatic bottom-up filling of TSV-like trenches: Choline-based leveler containing two quaternary ammoniums

MJ Kim, Y Seo, HC Kim, Y Lee, S Choe, YG Kim… - Electrochimica …, 2015 - Elsevier
Abstract Through Silicon Via (TSV) technology is essential to accomplish 3-dimensional
packaging of electronics. Hence, more reliable and faster TSV filling by Cu electrodeposition …

Electroless Cu deposition on atomic layer deposited Ru as novel seed formation process in through-Si vias

F Inoue, H Philipsen, A Radisic, S Armini, Y Civale… - Electrochimica …, 2013 - Elsevier
High aspect ratio through Si vias (φ 2μm, depth 30μm) have been filled completely by Cu
electroplating using an electroless deposited Cu seed layer. The electroless Cu deposition …

[HTML][HTML] ToF-SIMS 3D analysis of thin films deposited in high aspect ratio structures via atomic layer deposition and chemical vapor deposition

AM Kia, N Haufe, S Esmaeili, C Mart, M Utriainen… - Nanomaterials, 2019 - mdpi.com
For the analysis of thin films, with high aspect ratio (HAR) structures, time-of-flight secondary
ion mass spectrometry (ToF-SIMS) overcomes several challenges in comparison to other …

Effects of novel inhibitor on galvanic corrosion of copper and cobalt and particle removal

S Tian, B Tan, B Gao, Q Wang, C Han… - ECS Journal of Solid …, 2019 - iopscience.iop.org
With the reduction of the feature of GLSI, cobalt (Co) became a novel barrier material due to
its low resistivity and adhesion ability. On account of the different physical and chemical …

Bottom-up filling of through silicon vias using galvanostatic Cu electrodeposition with the modified organic additives

HC Kim, S Choe, JY Cho, D Lee, I Jung… - Journal of The …, 2014 - iopscience.iop.org
The chemically synthesized suppressor and leveler are added together with bis (3-
sulfopropyl) disulfide (SPS) to galvanostatically fill up the trenches with the similar …

Electroless copper bath stability monitoring with UV-Vis spectroscopy, pH, and mixed potential measurements

F Inoue, H Philipsen, A Radisic, S Armini… - Journal of The …, 2012 - iopscience.iop.org
Bath stability monitoring of electroless copper deposition has been done with different
methods. A combination of UV-VIS spectra and pH measurement enabled us to determine …

Vapor deposition of highly conformal copper seed layers for plating through-silicon vias (TSVs)

Y Au, QM Wang, H Li, JSM Lehn… - Journal of The …, 2012 - iopscience.iop.org
Through-silicon vias (TSV) will speed up interconnections between chips. Manufacturable
and cost-effective TSVs will allow faster computer systems. In this paper, we report the …

Additives for bottom-up copper plating from an alkaline complexed electrolyte

A Joi, R Akolkar, U Landau - Journal of The Electrochemical …, 2013 - iopscience.iop.org
An alkaline, tartrate-complexed copper electrolyte containing additives that provide bottom-
up fill is described. Bottom-up fill is achieved using a mixture of two additives: bis-(3 …

Enhanced barrier seed metallization for integration of high-density high aspect-ratio copper-filled 3D through-silicon via interconnects

Y Civale, S Armini, H Philipsen… - 2012 IEEE 62nd …, 2012 - ieeexplore.ieee.org
Higher performance, higher operation speed and volume shrinkage require high 3D
interconnect densities. A way to meet the density specifications is to further increase the AR …