Double Spin with a Twist: Synthesis and Characterization of a Neutral Mixed-Valence Organic Stable Diradical
A convenient design strategy opens access to neutral open-shell mixed-valence species via
the redox transformation of charged stable precursors, ie, the spiro-fused borate anions. We …
the redox transformation of charged stable precursors, ie, the spiro-fused borate anions. We …
Accelerated diradical character assessment in large datasets of polybenzenoid hydrocarbons using xTB fractional occupation
Polybenzenoid hydrocarbons (PBHs) have garnered significant attention in the field of
organic electronics due to their unique electronic properties. To facilitate the design and …
organic electronics due to their unique electronic properties. To facilitate the design and …
Unprecedented C–F bond cleavage in perfluoronaphthalene during cobaltocene reduction
The C–F bond activation of perfluoronaphthalene by 5-SIDipp led to the formation of
dicationic salts with two fluorides (3· 2HF2) or heptafluorodiborate (3· 2B2F7) as counter …
dicationic salts with two fluorides (3· 2HF2) or heptafluorodiborate (3· 2B2F7) as counter …