Second sphere effects on oxygen reduction and peroxide activation by mononuclear iron porphyrins and related systems
Activation and reduction of O2 and H2O2 by synthetic and biosynthetic iron porphyrin
models have proved to be a versatile platform for evaluating second-sphere effects deemed …
models have proved to be a versatile platform for evaluating second-sphere effects deemed …
Molecular electrocatalysts for the oxygen reduction reaction
The past decade has seen considerable growth in the development of materials for fuel cell
electrodes, and there is a desire for active electrocatalysts derived from base metals instead …
electrodes, and there is a desire for active electrocatalysts derived from base metals instead …
Inspiration from Nature: influence of engineered ligand scaffolds and auxiliary factors on the reactivity of biomimetic oxidants
Enzymes are highly efficient catalysts in Nature that often react with high stereo-, chemo-,
and regioselectivity. Usually, enzymes achieve this selectivity through substrate binding and …
and regioselectivity. Usually, enzymes achieve this selectivity through substrate binding and …
The chemistry, recent advancements and activity descriptors for macrocycles based electrocatalysts in oxygen reduction reaction
The oxygen reduction response (ORR) shows sluggish kinetics on cathode surface, which
welcomes a noteworthy commitment to the efficiency loss of the fuel cell devices. The …
welcomes a noteworthy commitment to the efficiency loss of the fuel cell devices. The …
Metalloporphyrin doped rice husk-based biomass porous carbon materials as high performance electrocatalyst for oxygen reduction reaction in Zn-Air battery
WY **e, C Ling, ZY Huang, WC Chen, SF He… - International Journal of …, 2024 - Elsevier
Rice husk (RH) is one of the most abundant biomass having a unique natural structure.
Herein, the highly porous rice husk carbon material (RHC) has been prepared. After loading …
Herein, the highly porous rice husk carbon material (RHC) has been prepared. After loading …
Recent advances in metalloporphyrins for environmental and energy applications
Porphyrin-based chemistry has reached an unprecedented period of rapid development
after decades of study. Due to attractive multifunctional properties, porphyrins and their …
after decades of study. Due to attractive multifunctional properties, porphyrins and their …
Concerted Proton–Electron Transfer in Electrocatalytic O2 Reduction by Iron Porphyrin Complexes: Axial Ligands Tuning H/D Isotope Effect
The electrochemical O2 reduction by thiolate-and imidazole-bound iron porphyrin
complexes and H/D isotope effects on 4e–(determined by rotating disc electrochemistry) and …
complexes and H/D isotope effects on 4e–(determined by rotating disc electrochemistry) and …
Tailor made iron porphyrins for investigating axial ligand and distal environment contributions to electronic structure and reactivity
Heme proteins catalyse a diverse set of vital life processes using very similar heme cofactor.
Thus, the inorganic chemistry community has been investigating factors in the protein active …
Thus, the inorganic chemistry community has been investigating factors in the protein active …
Resonance Raman and electrocatalytic behavior of thiolate and imidazole bound iron porphyrin complexes on self assembled monolayers: Functional modeling of …
Electrodes bearing thiolate and imidazole coordinated iron porphyrin catalysts are
constructed and characterized using resonance Raman spectroscopy, absorption …
constructed and characterized using resonance Raman spectroscopy, absorption …
Heme-copper and Heme O2-derived synthetic (bioinorganic) chemistry toward an understanding of cytochrome c oxidase dioxygen chemistry
Cytochrome c oxidase (CcO), also widely known as mitochondrial electron-transport-chain
complex IV, is a multi-subunit transmembrane protein responsible for catalyzing the last step …
complex IV, is a multi-subunit transmembrane protein responsible for catalyzing the last step …