Enantioconvergent catalysis has expanded asymmetric synthesis to new methodologies
able to convert racemic compounds into a single enantiomer. This review covers recent …

Functionalized oxindoles are privileged heterocyclic scaffolds and common core structural
motifs that are broadly present in numerous natural products and serve as key intermediates …

One central challenge for XXI century chemists is the development of sustainable processes
that do not represent a risk either to humanity or to the environment. In this regard, the …

Catalytic enantioselective synthesis methodologies have been actively explored and
developed owing to the significance of chiral molecules and their utilities. In particular …

Highly enantioselective rhodium‐catalyzed addition of arylboroxines to N‐unprotected
ketimines is realized for the first time by employing chiral BIBOP‐type ligands with a Rh …

Isatin is an important building block in organic synthesis. The electron‐deficient carbonyl in
C‐3 site is similar to aldehyde. C‐3 carbonyl is also able to function as the O‐nucleophile …

The development of enantiodivergent catalysis for the preparation of both enantiomers of a
chiral compound is of importance in pharmaceutical and bioorganic chemistry. With the …

Asymmetric Mannich-type addition of 3, 5-disubstituted-4-nitroisoxazoles to isatin-derived
Boc-protected imines has been realized by using 0.01 equiv of amide phosphonium salt as …

New chiral ligands could be obtained by introducing proline moieties and imidazoline
moieties to binaphthyl skeletons. The chiral ligands exhibited balanced rigidity and flexibility …

3-Substituted-3-aminooxindoles are versatile scaffolds and they are common core structural
motifs found in many natural products and biologically active compounds. In the last few …