Although C–H functionalization is one of the simplest reactions, it requires the use of highly
active and selective catalysts. Recently, C–H-active transformations using porous materials …

The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …

Abstract Im Jahr 2010 wurden Richard Heck, Ei‐ichi Negishi und Akira Suzuki in den
illustren Kreis der Chemie‐Nobelpreisträger aufgenommen. Begründet wurde diese …

Das Gebiet der übergangsmetallkatalysierten direkten Arylierung unter C‐H‐Bindungsbruch
hat in den letzten Jahren eine rasante Entwicklung erfahren, was dazu führte, dass sich …

Within the wide family of gold-catalyzed reactions, gold photocatalysis intrinsically features
unique elementary steps. When gold catalysis meets photocatalysis, a valence change of …

Research and industrial interest in radical C–H activation/radical cross-coupling chemistry
has continuously grown over the past few decades. These reactions offer fascinating and …

Pd-catalyzed cross-coupling reactions have become essential tools for the construction of
carbon–carbon and carbon–heteroatom bonds. Over the last three decades, great efforts …

BACKGROUND The development of useful new methods for the construction of carbon-
carbon bonds has had an impact on the many scientific disciplines (including materials …

Classical methods for achieving nucleophilic substitutions of alkyl electrophiles (SN1 and
SN2) have limited scope and are not generally amenable to enantioselective variants that …

The enantioselective synthesis of molecules containing quaternary stereocenters is a field of
intense research interest and development. Among the known organic transformations …