3d single-ion magnets
One of the determining factors in whether single-molecule magnets (SMMs) may be used as
the smallest component of data storage, is the size of the barrier to reversal of the …
the smallest component of data storage, is the size of the barrier to reversal of the …
Magnetic anisotropy in two-to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism
This review considers the most recent experimental developments in the magnetic
anisotropy of mono-nuclear transition metal complexes in various coordination …
anisotropy of mono-nuclear transition metal complexes in various coordination …
A trigonal prismatic mononuclear cobalt (II) complex showing single-molecule magnet behavior
Single-molecule magnets (SMMs) with one transition-metal ion often rely on unusual
geometry as a source of magnetically anisotropic ground state. Here we report a cobalt (II) …
geometry as a source of magnetically anisotropic ground state. Here we report a cobalt (II) …
First principles approach to the electronic structure, magnetic anisotropy and spin relaxation in mononuclear 3d-transition metal single molecule magnets
In this review, a self-contained (although brief) introduction to electronic structure
calculations for single molecule magnet (SMM) properties is provided in conjunction with …
calculations for single molecule magnet (SMM) properties is provided in conjunction with …
Role of Coordination Number and Geometry in Controlling the Magnetic Anisotropy in FeII, CoII, and NiII Single‐Ion Magnets
Since the last decade, the focus in the area of single‐molecule magnets (SMMs) has been
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
shifting constructively towards the development of single‐ion magnets (SIMs) based on …
Synthesis, Electronic Structure, and Magnetism of [Ni(6-Mes)2]+: A Two-Coordinate Nickel(I) Complex Stabilized by Bulky N-Heterocyclic Carbenes
RC Poulten, MJ Page, AG Algarra… - Journal of the …, 2013 - ACS Publications
The two-coordinate cationic Ni (I) bis-N-heterocyclic carbene complex [Ni (6-Mes) 2] Br (1)[6-
Mes= 1, 3-bis (2, 4, 6-trimethylphenyl)-3, 4, 5, 6-tetrahydropyrimidin-2-ylidene] has been …
Mes= 1, 3-bis (2, 4, 6-trimethylphenyl)-3, 4, 5, 6-tetrahydropyrimidin-2-ylidene] has been …
Pushing the limits of magnetic anisotropy in trigonal bipyramidal Ni (II)
KER Marriott, L Bhaskaran, C Wilson, M Medarde… - Chemical …, 2015 - pubs.rsc.org
Monometallic complexes based on 3d transition metal ions in certain axial coordination
environments can exhibit appreciably enhanced magnetic anisotropy, important for memory …
environments can exhibit appreciably enhanced magnetic anisotropy, important for memory …
Ising-type magnetic anisotropy and single molecule magnet behaviour in mononuclear trigonal bipyramidal Co (II) complexes
R Ruamps, LJ Batchelor, R Guillot, G Zakhia… - Chemical …, 2014 - pubs.rsc.org
The magnetic anisotropy of two pentacoordinate trigonal bipyramidal (C3v symmetry) Co (II)
complexes,[Co (Me6tren) Cl] ClO4 (1) and [Co (Me6tren) Br] Br (2), was investigated and …
complexes,[Co (Me6tren) Cl] ClO4 (1) and [Co (Me6tren) Br] Br (2), was investigated and …
A mononuclear transition metal single-molecule magnet in a nuclear spin-free ligand environment
MS Fataftah, JM Zadrozny, DM Rogers… - Inorganic …, 2014 - ACS Publications
The high-spin pseudotetrahedral complex [Co (C3S5) 2] 2–exhibits slow magnetic
relaxation in the absence of an applied dc magnetic field, one of a small number of …
relaxation in the absence of an applied dc magnetic field, one of a small number of …
Observation of the single-ion magnet behavior of d 8 ions on two-coordinate Co (I)–NHC complexes
YS Meng, Z Mo, BW Wang, YQ Zhang, L Deng… - Chemical …, 2015 - pubs.rsc.org
The slow magnetic relaxation typical for single-ion magnets has been known for certain low-
coordinate 3d metal complexes with d6, d7, and d9 electronic configurations, but never for …
coordinate 3d metal complexes with d6, d7, and d9 electronic configurations, but never for …