Activation of dinitrogen by polynuclear metal complexes
Activation of dinitrogen plays an important role in daily anthropogenic life, and the processes
by which this fixation occurs have been a longstanding and significant research focus within …
by which this fixation occurs have been a longstanding and significant research focus within …
A DFT perspective on organometallic lanthanide chemistry
Computational studies of the coordination chemistry and bonding of lanthanides have grown
in recent decades as the need for understanding the distinct physical, optical, and magnetic …
in recent decades as the need for understanding the distinct physical, optical, and magnetic …
A rare-earth metal retrospective to stimulate all fields
Formulating insightful questions and experiments is crucial to the advancement of science.
The purpose of this Perspective is to encourage scientists in all areas of chemistry to ask …
The purpose of this Perspective is to encourage scientists in all areas of chemistry to ask …
Completing the Series of +2 Ions for the Lanthanide Elements: Synthesis of Molecular Complexes of Pr2+, Gd2+, Tb2+, and Lu2+
MR MacDonald, JE Bates, JW Ziller… - Journal of the …, 2013 - ACS Publications
The first examples of crystallographically characterizable complexes of Tb2+, Pr2+, Gd2+,
and Lu2+ have been isolated, which demonstrate that Ln2+ ions are accessible in soluble …
and Lu2+ have been isolated, which demonstrate that Ln2+ ions are accessible in soluble …
Tutorial on the Role of Cyclopentadienyl Ligands in the Discovery of Molecular Complexes of the Rare-Earth and Actinide Metals in New Oxidation States 136
WJ Evans - Organometallics, 2016 - ACS Publications
A fundamental aspect of any element is the range of oxidation states accessible for useful
chemistry. This tutorial describes the recent expansion of the number of oxidation states …
chemistry. This tutorial describes the recent expansion of the number of oxidation states …
Small molecule activation by uranium tris (aryloxides): experimental and computational studies of binding of N2, coupling of CO, and deoxygenation insertion of CO2 …
Previously unanticipated dinitrogen activation is exhibited by the well-known uranium tris
(aryloxide) U (ODtbp) 3, U (OC6H3-But2-2, 6) 3, and the tri-tert-butyl analogue U (OTtbp) 3 …
(aryloxide) U (ODtbp) 3, U (OC6H3-But2-2, 6) 3, and the tri-tert-butyl analogue U (OTtbp) 3 …
Expanding rare-earth oxidation state chemistry to molecular complexes of holmium (II) and erbium (II)
The first molecular complexes of holmium and erbium in the+ 2 oxidation state have been
generated by reducing Cp′ 3Ln [Cp′= C5H4SiMe3; Ln= Ho (1), Er (2)] with KC8 in the …
generated by reducing Cp′ 3Ln [Cp′= C5H4SiMe3; Ln= Ho (1), Er (2)] with KC8 in the …
Scandium-promoted direct conversion of dinitrogen into hydrazine derivatives via N–C bond formation
ZJ Lv, Z Huang, WX Zhang, Z ** - Journal of the American …, 2019 - ACS Publications
Direct conversion of dinitrogen (N2) into organic compounds, not through ammonia (NH3), is
of great significance both fundamentally and practically. Here we report a highly efficient …
of great significance both fundamentally and practically. Here we report a highly efficient …
Synthesis of a Crystalline Molecular Complex of Y2+, [(18-crown-6)K][(C5H4SiMe3)3Y]
MR MacDonald, JW Ziller… - Journal of the American …, 2011 - ACS Publications
The La2+ complex [K (18-crown-6)(OEt2)][Cp ″3La](1)[Cp ″= C5H3 (SiMe3) 2-1, 3], can
be synthesized under N2, but in the presence of KC5Me5, 1 reduces N2 to the (N N) 2 …
be synthesized under N2, but in the presence of KC5Me5, 1 reduces N2 to the (N N) 2 …
Solution Synthesis, Structure, and CO2 Reduction Reactivity of a Scandium(II) Complex, {Sc[N(SiMe3)2]3}−
The first crystallographically characterizable complex of Sc2+,[Sc (NR2) 3]−(R= SiMe3), has
been obtained by LnA3/M reactions (Ln= rare earth metal; A= anionic ligand; M= alkali …
been obtained by LnA3/M reactions (Ln= rare earth metal; A= anionic ligand; M= alkali …