Complex formation and cytotoxicity of Triapine derivatives: A comparative solution study on the effect of the chalcogen atom and NH-methylation
α-N-Heterocyclic thiosemicarbazones are an important class of investigational anticancer
drugs. The most prominent representative is 3-aminopyridine-2-carboxaldehyde …
drugs. The most prominent representative is 3-aminopyridine-2-carboxaldehyde …
Kinetico-Mechanistic Studies on a Reactive Organocopper (II) Complex: Cu–C Bond Homolysis versus Heterolysis
Organocopper (II) reagents are an unexplored frontier of copper catalysis. Despite being
proposed as reactive intermediates, an understanding of the stability and reactivity of the …
proposed as reactive intermediates, an understanding of the stability and reactivity of the …
Fe (ii) complexes of pyridine-substituted thiosemicarbazone ligands as catalysts for oxidations with hydrogen peroxide
The reaction of three [FeII (TSC) 2] complexes, where TSC is a pyridine-substituted
thiosemicarbazone of the HDpT or HBpT families, with H2O2 in acetonitrile solution does not …
thiosemicarbazone of the HDpT or HBpT families, with H2O2 in acetonitrile solution does not …
A detailed kinetico-mechanistic investigation on the palladium C–H bond activation in azobenzenes and their monopalladated derivatives
Palladium C–H bond activation in azobenzenes with R1 and R2 at para positions of the
phenyl rings (R1= NMe2, R2= H (L1); R1= NMe2, R2= Cl (L2); R1= NMe2, R2= I (L3); R1 …
phenyl rings (R1= NMe2, R2= H (L1); R1= NMe2, R2= Cl (L2); R1= NMe2, R2= I (L3); R1 …
Thiosemicarbazone-metal complexes exhibiting cytotoxicity in colon cancer cell lines through oxidative stress
Colorectal cancer is the third most common type of cancer and has a high incidence in
developed countries. At present, specific treatments are being required to allow …
developed countries. At present, specific treatments are being required to allow …
Molecular Approach to Alkali-Metal Encapsulation by a Prussian Blue Analogue FeII/CoIII Cube in Aqueous Solution: A Kineticomechanistic Exchange Study
The preparation of a series of alkali-metal inclusion complexes of the molecular cube [{CoIII
(Me3-tacn)} 4 {FeII (CN) 6} 4] 4–(Me3-tacn= 1, 4, 7-trimethyl-1, 4, 7-triazacyclononane), a …
(Me3-tacn)} 4 {FeII (CN) 6} 4] 4–(Me3-tacn= 1, 4, 7-trimethyl-1, 4, 7-triazacyclononane), a …
Kineticomechanistic Study of the Redox pH Cycling Processes Occurring on a Robust Water-Soluble Cyanido-Bridged Mixed-Valence {CoIII/FeII}2 Square
L Alcázar, PV Bernhardt, M Ferrer… - Inorganic …, 2018 - ACS Publications
A kineticomechanistic study of reversible electron-transfer processes undergone by the
water-soluble, cyanido-bridged mixed-valence [{CoIII {(Me) 2 (μ-ET) cyclen}} 2 {(μ-NC) 2FeII …
water-soluble, cyanido-bridged mixed-valence [{CoIII {(Me) 2 (μ-ET) cyclen}} 2 {(μ-NC) 2FeII …
Proton-assisted air oxidation mechanisms of iron (II) bis-thiosemicarbazone complexes at physiological pH: a kinetico-mechanistic study
The kinetics of oxidation of different biologically-active FeII bis-thiosemicarbazone
complexes in water has been monitored at varying dioxygen concentration, temperature …
complexes in water has been monitored at varying dioxygen concentration, temperature …
Cu (II)-induced twisting of the biphenyl core: exploring the effect of structure and coordination environment of biphenyl-based chiral copper (II) complexes on …
Three new clip-like receptors (H2L1, H2L2, and H2L3) have been synthesized based on a
biphenyl moiety consisting of two amide and Schiff base linkages, and used to prepare the …
biphenyl moiety consisting of two amide and Schiff base linkages, and used to prepare the …
Kinetic compensation effect: discounting the distortion provoked by accidental experimental errors in the isokinetic temperature value
JF Perez-Benito, I Alburquerque-Alvarez - Monatshefte für Chemie …, 2020 - Springer
Random experimental errors are known to provoke the appearance of false isokinetic
enthalpy–entropy relationships under some circumstances. In this contribution, it is shown …
enthalpy–entropy relationships under some circumstances. In this contribution, it is shown …