Best‐practice DFT protocols for basic molecular computational chemistry

M Bursch, JM Mewes, A Hansen… - Angewandte Chemie …, 2022 - Wiley Online Library
Nowadays, many chemical investigations are supported by routine calculations of molecular
structures, reaction energies, barrier heights, and spectroscopic properties. The lion's share …

[HTML][HTML] Software for the frontiers of quantum chemistry: An overview of developments in the Q-Chem 5 package

E Epifanovsky, ATB Gilbert, X Feng, J Lee… - The Journal of …, 2021 - pubs.aip.org
This article summarizes technical advances contained in the fifth major release of the Q-
Chem quantum chemistry program package, covering developments since 2015. A …

Advances in molecular quantum chemistry contained in the Q-Chem 4 program package

Y Shao, Z Gan, E Epifanovsky, ATB Gilbert… - Molecular …, 2015 - Taylor & Francis
A summary of the technical advances that are incorporated in the fourth major release of the
q-Chem quantum chemistry program is provided, covering approximately the last seven …

DFT exchange: sharing perspectives on the workhorse of quantum chemistry and materials science

AM Teale, T Helgaker, A Savin, C Adamo… - Physical chemistry …, 2022 - pubs.rsc.org
In this paper, the history, present status, and future of density-functional theory (DFT) is
informally reviewed and discussed by 70 workers in the field, including molecular scientists …

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

S Grimme, J Antony, S Ehrlich, H Krieg - The Journal of chemical …, 2010 - pubs.aip.org
The method of dispersion correction as an add-on to standard Kohn–Sham density
functional theory (DFT-D) has been refined regarding higher accuracy, broader range of …

Eliminating nonradiative decay in Cu (I) emitters:> 99% quantum efficiency and microsecond lifetime

R Hamze, JL Peltier, D Sylvinson, M Jung, J Cardenas… - Science, 2019 - science.org
Luminescent complexes of heavy metals such as iridium, platinum, and ruthenium play an
important role in photocatalysis and energy conversion applications as well as organic light …

Perspective: Advances and challenges in treating van der Waals dispersion forces in density functional theory

J Klimeš, A Michaelides - The Journal of chemical physics, 2012 - pubs.aip.org
Electron dispersion forces play a crucial role in determining the structure and properties of
biomolecules, molecular crystals, and many other systems. However, an accurate …

Efficient and Accurate Double-Hybrid-Meta-GGA Density Functionals Evaluation with the Extended GMTKN30 Database for General Main Group Thermochemistry …

L Goerigk, S Grimme - Journal of chemical theory and …, 2011 - ACS Publications
We present an extended and improved version of our recently published database for
general main group thermochemistry, kinetics, and noncovalent interactions [J. Chem …

Stabilizing and modulating color by copigmentation: Insights from theory and experiment

P Trouillas, JC Sancho-García, V De Freitas… - Chemical …, 2016 - ACS Publications
Natural anthocyanin pigments/dyes and phenolic copigments/co-dyes form noncovalent
complexes, which stabilize and modulate (in particular blue, violet, and red) colors in …

Minimally empirical double-hybrid functionals trained against the GMTKN55 database: revDSD-PBEP86-D4, revDOD-PBE-D4, and DOD-SCAN-D4

G Santra, N Sylvetsky, JML Martin - The Journal of Physical …, 2019 - ACS Publications
We present a family of minimally empirical double-hybrid DFT functionals parametrized
against the very large and diverse GMTKN55 benchmark. The very recently proposed …