Optical phenomena in molecule-based magnetic materials

JJ Zakrzewski, M Liberka, J Wang, S Chorazy… - Chemical …, 2024 - ACS Publications
Since the last century, we have witnessed the development of molecular magnetism which
deals with magnetic materials based on molecular species, ie, organic radicals and metal …

Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Shining new light on multifunctional lanthanide single‐molecule magnets

R Marin, G Brunet, M Murugesu - … Chemie International Edition, 2021 - Wiley Online Library
Single‐molecule magnets (SMMs) are at the forefront of new technological advances in
quantum information processing and spintronics. Despite the recent impressive …

Giant coercivity and high magnetic blocking temperatures for N23− radical-bridged dilanthanide complexes upon ligand dissociation

S Demir, MI Gonzalez, LE Darago, WJ Evans… - Nature …, 2017 - nature.com
Increasing the operating temperatures of single-molecule magnets—molecules that can
retain magnetic polarization in the absence of an applied field—has potential implications …

Lanthanide–radical single-molecule magnets: current status and future challenges

HD Li, SG Wu, ML Tong - Chemical Communications, 2023 - pubs.rsc.org
In the field of molecular magnetism, the lanthanide–radical (Ln–Rad) method has become
one of the most appealing tactics for introducing strong magnetic interactions and has …

Recent advances in luminescent lanthanide based Single-Molecule Magnets

J Long, Y Guari, RAS Ferreira, LD Carlos… - Coordination Chemistry …, 2018 - Elsevier
Abstract Luminescent lanthanide-based Single-Molecule Magnets (SMM) are multifunctional
molecule-based materials that combine luminescence and magnetic properties in the same …

Cyclopentadienyl ligands in lanthanide single-molecule magnets: one ring to rule them all?

BM Day, FS Guo, RA Layfield - Accounts of Chemical Research, 2018 - ACS Publications
Conspectus The discovery of materials capable of storing magnetic information at the level
of single molecules and even single atoms has fueled renewed interest in the slow magnetic …

Main group chemistry at the interface with molecular magnetism

FS Guo, AK Bar, RA Layfield - Chemical Reviews, 2019 - ACS Publications
Innovative synthetic coordination and, increasingly, organometallic chemistry are at the
heart of advances in molecular magnetism. Smart ligand design is essential for …

Substituent effects on exchange coupling and magnetic relaxation in 2, 2′-bipyrimidine radical-bridged dilanthanide complexes

CA Gould, E Mu, V Vieru, LE Darago… - Journal of the …, 2020 - ACS Publications
Systematic analysis of related compounds is crucial to the design of single-molecule
magnets with improved properties, yet such studies on multinuclear lanthanide complexes …

Hard single-molecule magnet behavior and strong magnetic coupling in pyrazinyl radical-bridged lanthanide metallocenes

N Bajaj, N Mavragani, AA Kitos, D Chartrand, T Maris… - Chem, 2024 - cell.com
Contemporary lifestyle is interwoven with technological achievements that implement the
use of permanent magnets. Polynuclear lanthanide single-molecule magnets (SMMs) lack …