Methane oxidation to methanol

NF Dummer, DJ Willock, Q He, MJ Howard… - Chemical …, 2022 - ACS Publications
The direct transformation of methane to methanol remains a significant challenge for
operation at a larger scale. Central to this challenge is the low reactivity of methane at …

Metal-organic framework-based heterogeneous catalysts for the conversion of C1 chemistry: CO, CO2 and CH4

WG Cui, GY Zhang, TL Hu, XH Bu - Coordination Chemistry Reviews, 2019 - Elsevier
Catalysis of C1 chemistry, especially for carbon monoxide (CO), carbon dioxide (CO 2) and
methane (CH 4), is critically important for the clean production of fuels and chemicals and …

Solar-energy-mediated methane conversion

H Song, X Meng, Z Wang, H Liu, J Ye - Joule, 2019 - cell.com
The conversion of methane to upgraded fuels and higher-value chemicals such as
hydrogen, methanol, and olefins is a promising technology in the supply of chemicals and …

Active sites and mechanisms in the direct conversion of methane to methanol using Cu in zeolitic hosts: a critical examination

MA Newton, AJ Knorpp, VL Sushkevich… - Chemical Society …, 2020 - pubs.rsc.org
In this critical review we examine the current state of our knowledge in respect of the nature
of the active sites in copper containing zeolites for the selective conversion of methane to …

The nuclearity of the active site for methane to methanol conversion in Cu-mordenite: a quantitative assessment

DK Pappas, A Martini, M Dyballa… - Journal of the …, 2018 - ACS Publications
The direct conversion of methane to methanol (MTM) is a reaction that has the potential to
disrupt a great part of the synthesis gas-derived chemical industry. However, despite many …

Correlating the Valence State with the Adsorption Behavior of a Cu‐Based Electrocatalyst for Furfural Oxidation with Anodic Hydrogen Production Reaction

M Yang, Y Li, CL Dong, S Li, L Xu, W Chen… - Advanced …, 2023 - Wiley Online Library
The low‐potential furfural oxidation reaction (FFOR) on a Cu‐based electrocatalyst can
produce H2 at the anode, thereby providing a bipolar H2 production system with an ultralow …

Synthetic Fe/Cu complexes: toward understanding heme-copper oxidase structure and function

SM Adam, GB Wijeratne, PJ Rogler, DE Diaz… - Chemical …, 2018 - ACS Publications
Heme-copper oxidases (HCOs) are terminal enzymes on the mitochondrial or bacterial
respiratory electron transport chain, which utilize a unique heterobinuclear active site to …

Methane selective oxidation to methanol by metal-exchanged zeolites: a review of active sites and their reactivity

MH Mahyuddin, Y Shiota, K Yoshizawa - Catalysis Science & …, 2019 - pubs.rsc.org
Over the past decade, zeolites (microporous aluminosilicate minerals) have been gaining
significant popularity due to their broad applications in catalysis including the dream …

Copper nanoparticles encapsulated in zeolitic imidazolate framework-8 as a stable and selective CO2 hydrogenation catalyst

VK Velisoju, JL Cerrillo, R Ahmad… - Nature …, 2024 - nature.com
Metal–organic frameworks have drawn attention as potential catalysts owing to their unique
tunable surface chemistry and accessibility. However, their application in thermal catalysis …

Misconceptions and challenges in methane-to-methanol over transition-metal-exchanged zeolites

M Ravi, VL Sushkevich, AJ Knorpp, MA Newton… - Nature Catalysis, 2019 - nature.com
Direct methane functionalization and, in particular, the selective partial oxidation to
methanol, remains an eminent challenge and a field of competitive research. The …