Organometallic chemistry and its applications in homogeneous catalysis have been
dominated by mononuclear transition-metal complexes. The catalytic performance and …

Computational chemistry provides a versatile toolbox for studying mechanistic details of
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …

Significant progress has been made in the past 10–15 years on the design, synthesis, and
properties of multimetallic coordination complexes with heterometallic metal–metal bonds …

Despite being weak attractive forces, closed‐shell metallophilic interactions play important
roles in the Group 11 metal complexes on their diverse structural and physical features. A …

There is growing interest in the design of bimetallic cooperative complexes, which have
emerged due to their potential for bond activation and catalysis, a feature widely exploited …

Cluster complexes have attracted interest for decades due to their promise of drawing
analogies to metallic surfaces and metalloenzyme active sites, but only recently have …

Heterobi-and multimetallic complexes providing close proximity between several metal
centers serve as active species in artificial and enzymatic catalysis, and in model systems …

Conspectus Bimetallic motifs are a structural feature common to some of the most effective
and synthetically useful catalysts known, including in the active sites of many …

Heterobimetallic complexes are studied for their ability to mimic biological systems as well
as active sites in heterogeneous catalysts. While specific interest in early/late …

We report the preparation of UFe (CO) 3− and OUFe (CO) 3− complexes using a laser‐
vaporization supersonic ion source in the gas phase. These compounds were mass …