Metal–ligand cooperation
Metal–ligand cooperation (MLC) has become an important concept in catalysis by transition
metal complexes both in synthetic and biological systems. MLC implies that both the metal …
metal complexes both in synthetic and biological systems. MLC implies that both the metal …
Brønsted–Lowry acid strength of metal hydride and dihydrogen complexes
RH Morris - Chemical Reviews, 2016 - ACS Publications
Transition metal hydride complexes are usually amphoteric, not only acting as hydride
donors, but also as Brønsted–Lowry acids. A simple additive ligand acidity constant …
donors, but also as Brønsted–Lowry acids. A simple additive ligand acidity constant …
Catalytic Furfural/5-Hydroxymethyl Furfural Oxidation to Furoic Acid/Furan-2,5-dicarboxylic Acid with H2 Production Using Alkaline Water as the Formal Oxidant
S Kar, QQ Zhou, Y Ben-David… - Journal of the American …, 2022 - ACS Publications
Furfural and 5-hydroxymethyl furfural (HMF) are abundantly available biomass-derived
renewable chemical feedstocks, and their oxidation to furoic acid and furan-2, 5-dicarboxylic …
renewable chemical feedstocks, and their oxidation to furoic acid and furan-2, 5-dicarboxylic …
Oxidative R1–H/R2–H Cross-Coupling with Hydrogen Evolution
Oxidative R1–H/R2–H cross-coupling with hydrogen evolution serves as one of the most
atom-economical methods for constructing new chemical bonds. This reaction strategy …
atom-economical methods for constructing new chemical bonds. This reaction strategy …
Efficient base-free aqueous reforming of methanol homogeneously catalyzed by ruthenium exhibiting a remarkable acceleration by added catalytic thiol
Production of H2 by methanol reforming is of particular interest due the low cost, ready
availability, and high hydrogen content of methanol. However, most current methods either …
availability, and high hydrogen content of methanol. However, most current methods either …
Oxidation of Organic Compounds Using Water as the Oxidant with H2 Liberation Catalyzed by Molecular Metal Complexes
S Kar, D Milstein - Accounts of chemical research, 2022 - ACS Publications
Conspectus Oxidation reactions of organic compounds play a central role in both industrial
chemical and material synthesis as well as in fine chemical and pharmaceutical synthesis …
chemical and material synthesis as well as in fine chemical and pharmaceutical synthesis …
Synthesis of pyrazines and quinoxalines via acceptorless dehydrogenative coupling routes catalyzed by manganese pincer complexes
Base-metal catalyzed dehydrogenative self-coupling of 2-amino alcohols to selectively form
functionalized 2, 5-substituted pyrazine derivatives is presented. Also, 2-substituted …
functionalized 2, 5-substituted pyrazine derivatives is presented. Also, 2-substituted …
Highly efficient process for production of biofuel from ethanol catalyzed by ruthenium pincer complexes
Y **e, Y Ben-David, LJW Shimon… - Journal of the American …, 2016 - ACS Publications
A highly efficient ruthenium pincer-catalyzed Guerbet-type process for the production of
biofuel from ethanol has been developed. It produces the highest conversion of ethanol …
biofuel from ethanol has been developed. It produces the highest conversion of ethanol …
Sustainable catalysis with fluxional acridine-based PNP pincer complexes
S Kar, D Milstein - Chemical Communications, 2022 - pubs.rsc.org
Because of the widespread use of fossil fuels and the resulting global warming,
development of sustainable catalytic transformations is now more important than ever to …
development of sustainable catalytic transformations is now more important than ever to …
Ruthenium-Catalyzed ortho Alkenylation of Aromatics with Alkenes at Room Temperature with Hydrogen Evolution
A ruthenium-catalyzed oxidant-free highly regioselective ortho alkenylation of substituted
aromatics such as aromatic amides, aromatic ketoximes, and anilides with alkenes in the …
aromatics such as aromatic amides, aromatic ketoximes, and anilides with alkenes in the …