Cyclization reactions of bis (allenes) for the synthesis of polycarbo (hetero) cycles

B Alcaide, P Almendros, C Aragoncillo - Chemical Society Reviews, 2014 - pubs.rsc.org
The chemistry of allenes is an appealing topic which fascinates chemists nowadays. Their
reactivity and versatility makes this skeleton a useful moiety to create a great variety of …

Recent advances in Garratt-Braverman cyclization: Mechanistic and synthetic explorations

P Bhattacharya, M Singha, E Das, A Mandal, M Maji… - Tetrahedron …, 2018 - Elsevier
Garratt-Braverman cyclization has emerged as one of the simplest synthetic tool to construct
two consecutive Csingle bondC bonds leading to the formation of various important …

Pentacoordinate ruthenium (II) catecholthiolate and mercaptophenolate catalysts for olefin metathesis: anionic ligand exchange and ease of initiation

MS Mikus, S Torker, C Xu, B Li, AH Hoveyda - Organometallics, 2016 - ACS Publications
The investigations disclosed offer insight regarding several key features of Ru-based
catecholthiolate olefin metathesis catalysts. Factors influencing the facility with which the two …

Enediynes bearing polyfluoroaryl sulfoxide as new antiproliferative agents with dual targeting of microtubules and DNA

C Borie, S Mondal, T Arif, M Briand, H Lingua… - European Journal of …, 2018 - Elsevier
A novel series of enediynes possessing pentafluorophenylsulfoxide have been developed.
The innovative compounds possess antiproliferative activity against a broad panel of human …

A highly stable porous viologen polymer for the catalysis of debromination coupling of benzyl bromides with high recyclability

JK Tang, SB Yu, CZ Liu, H Wang… - Asian Journal of …, 2019 - Wiley Online Library
A highly stable porous organic polymer bipy‐POP has been prepared from the reaction of 4,
4′‐bipyridine and tetrakis (4‐(bromomethyl) phenyl) methane in N‐methylpyrrolidone at …

Garratt–Braverman cyclization, a powerful tool for C–C bond formation

S Mondal, T Mitra, R Mukherjee, PS Addy, A Basak - Synlett, 2012 - thieme-connect.com
Development of new strategies for C–C bond formation remains in the forefront of organic
synthesis. The base-mediated rearrangement of bis-propargyl sulfones via bis-allenes …

Selectfluor-Promoted Sequential Reactions via Allene Intermediates: Metal-Free Construction of Fused Polycyclic Skeletons

L Liu, J Wang, H Zhou - The Journal of Organic Chemistry, 2015 - ACS Publications
Selectfluor-Promoted Sequential Reactions via Allene Intermediates: Metal-Free Construction
of Fused Polycyclic Skeletons | The Journal of Organic Chemistry ACS ACS Publications C&EN …

Selectivity in Garratt–Braverman Cyclization of Aryl-/Heteroaryl-Substituted Unsymmetrical Bis-Propargyl Systems: Formal Synthesis of 7′-Desmethylkealiiquinone

J Das, R Mukherjee, A Basak - The Journal of Organic Chemistry, 2014 - ACS Publications
Unsymmetrical bis-propargyl ethers and sulfonamides containing various combinations of
aryl/heteroaryl substituents at the acetylene termini were synthesized, and their reactivity …

Synthesis of benzochromenes and dihydrophenanthridines with helical motifs using Garratt–Braverman and Buchwald–Hartwig reactions

P Bhattacharya, K Senapati, K Chattopadhyay… - RSC …, 2015 - pubs.rsc.org
A simple strategy for the synthesis of 6H-benzo [c] chromenes and 5, 6-
dihydrophenanthridines through a judicious use of Garratt–Braverman (GB) cyclization and …

Oxa-and Azacycle Formation via Migrative Cyclization of Sulfonylalkynol and Sulfonylalkynamide with N-Heterocyclic Carbene

Y Wang, R Oriez, S Kuwano, Y Yamaoka… - The Journal of …, 2016 - ACS Publications
An N-heterocyclic carbene promotes cyclization of sulfonylalkynols and sulfonylalkynamides
that accompanies 1, 2-migration of the sulfonyl groups. This reaction provides a novel …