Electrochemistry and photoluminescence of icosahedral carboranes, boranes, metallacarboranes, and their derivatives
Icosahedral boranes, carboranes, and metallacarboranes are extraordinarily robust
compounds with desirable properties such as thermal and redox stability, chemical …
compounds with desirable properties such as thermal and redox stability, chemical …
Transition metal-induced B–H functionalization of o-carborane
X Zhang, H Yan - Coordination Chemistry Reviews, 2019 - Elsevier
Transition metal-mediated B–H functionalization of carboranes has drawn increasing
interests during the last two decades. This review describes how to incorporate B–H …
interests during the last two decades. This review describes how to incorporate B–H …
Boron science
NS Hosmane - New technologies and applications, 2011 - api.taylorfrancis.com
What is boron? The question itself may not seem very significant to many people. Their
introduction to the word “boron” could come as the butt of a joke. Conan O'Brien made jokes …
introduction to the word “boron” could come as the butt of a joke. Conan O'Brien made jokes …
Carbon flatland: Planar tetracoordinate carbon and fenestranes
R Keese - Chemical reviews, 2006 - ACS Publications
The common structural features of optically active compounds, known in 1874, led van't Hoff
and, independently, Le Bel to the conclusion that tetracoordinate carbon compounds of type …
and, independently, Le Bel to the conclusion that tetracoordinate carbon compounds of type …
Synthesis and Properties of Carborane-Appended C3-Symmetrical Extended π Systems
A series of C 3-symmetric π-conjugated compounds containing three to six o-carborane
clusters have been synthesized by employing palladium-catalyzed Suzuki coupling …
clusters have been synthesized by employing palladium-catalyzed Suzuki coupling …
Transition metal− carboryne complexes: synthesis, bonding, and reactivity
Z Qiu, S Ren, Z **e - Accounts of chemical research, 2011 - ACS Publications
The construction and transformation of metal− carbon (M− C) bonds constitute the central
themes of organometallic chemistry. Most of the work in this field has focused on traditional …
themes of organometallic chemistry. Most of the work in this field has focused on traditional …
BH activation of carboranes induced by late transition metals
WB Yu, PF Cui, WX Gao, GX ** - Coordination Chemistry Reviews, 2017 - Elsevier
The selective and straightforward functionalization of Bsingle bondH bonds in carboranes,
producing new Csingle bondB bonds or metallacarboranes, has drawn increasing interest in …
producing new Csingle bondB bonds or metallacarboranes, has drawn increasing interest in …
Transition Metal Catalyzed Direct Amination of the Cage B(4)–H Bond in o-Carboranes: Synthesis of Tertiary, Secondary, and Primary o-Carboranyl Amines
Transition metal catalyzed regioselective amination of the cage B (4)–H bond in o-
carboranes has been achieved for the first time using O-benzoyl hydroxylamines or organic …
carboranes has been achieved for the first time using O-benzoyl hydroxylamines or organic …
Rhodium-Catalyzed Amidation of the Cage B(4)–H Bond in o-Carboranes with Dioxazolones by Carboxylic Acid-Assisted B(4)–H Bond Activation
A rhodium-catalyzed direct and regioselective amidation of the cage B (4)–H bond in a wide
range of o-carboranes with alkyl-, aryl-, and heteroaryl-substituted dioxazolones is …
range of o-carboranes with alkyl-, aryl-, and heteroaryl-substituted dioxazolones is …
Iridium-Catalyzed Selective B(4)–H Amination of o-Carboranes with Anthranils
LB Zhang, Z **e - Organic Letters, 2022 - ACS Publications
We report here a catalytic selective cage B4–H amination of o-carboranes employing an Ir
(III) complex as a catalyst and anthranils as aminating agents, leading to a large class of B4 …
(III) complex as a catalyst and anthranils as aminating agents, leading to a large class of B4 …