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[HTML][HTML] Review of transition-metal diboride thin films
We review the thin film growth, chemistry, and physical properties of Group 4–6 transition-
metal diboride (TMB 2) thin films with AlB 2-type crystal structure (Strukturbericht designation …
metal diboride (TMB 2) thin films with AlB 2-type crystal structure (Strukturbericht designation …
[HTML][HTML] Improving the high-temperature oxidation resistance of TiB2 thin films by alloying with Al
Refractory transition-metal diborides (TMB 2) are candidates for extreme environments due
to melting points above 3000° C, excellent hardness, good chemical stability, and thermal …
to melting points above 3000° C, excellent hardness, good chemical stability, and thermal …
[HTML][HTML] Oxidation kinetics of overstoichiometric TiB2 thin films grown by DC magnetron sputtering
We systematically study the oxidation properties of sputter-deposited TiB 2.5 coatings up to
700° C. Oxide-scale thickness d ox increases linearly with time ta for 300, 400, 500, and …
700° C. Oxide-scale thickness d ox increases linearly with time ta for 300, 400, 500, and …
[HTML][HTML] Thermal stability and mechanical properties of sputtered (Hf, Ta, V, W, Zr)-diborides
Non-reactive magnetron sputtering of a diboride target composed of HfB 2, TaB 2, VB 2, W 2
B 5, and ZrB 2 with equimolar composition leads to the formation of crystalline single-phase …
B 5, and ZrB 2 with equimolar composition leads to the formation of crystalline single-phase …
[HTML][HTML] Influence of Si on the oxidation behavior of TM-Si-B2ąz coatings (TM= Ti, Cr, Hf, Ta, W)
The concept of Si alloyed transition metal (TM) diborides–well explored for bulk ceramics–is
studied for five different physical vapor deposited TM-Si-B 2ąz (TM= Ti, Cr, Hf, Ta, W) …
studied for five different physical vapor deposited TM-Si-B 2ąz (TM= Ti, Cr, Hf, Ta, W) …
Anisotropic super-hardness of hexagonal WB2±z thin films
Transition metal diboride-based thin films are promising candidates to replace state-of-the-
art protective and functional coating materials due to their unique properties. Here, we focus …
art protective and functional coating materials due to their unique properties. Here, we focus …
[HTML][HTML] Impact of vacancies on structure, stability and properties of hexagonal transition metal diborides, MB2 (M= Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, and Fe)
In this study, we have used density functional theory (DFT) calculations to characterize if and
how defects influence the stability and electronic/mechanical properties of MB 2 (AlB 2-type) …
how defects influence the stability and electronic/mechanical properties of MB 2 (AlB 2-type) …
Structure evolution and mechanical properties of hard tantalum diboride films
Tantalum diboride (TaB 2) belonging to the ultrahigh temperature ceramics family is proving
to be a promising material for hard protective films, thanks to its high thermal stability and …
to be a promising material for hard protective films, thanks to its high thermal stability and …
[HTML][HTML] Effects of stoichiometry and individual layer thickness ratio on the quality of epitaxial CrBx/TiBy superlattice thin films
Studies of single crystal artificial superlattices (SLs) of transition-metal (TM) diborides, which
is instrumental to understand hardening mechanisms at nanoscale, is lacking. Here, CrB …
is instrumental to understand hardening mechanisms at nanoscale, is lacking. Here, CrB …
Mechanistic study of superlattice-enabled high toughness and hardness in MoN/TaN coatings
Machining and forming tools exposed to challenging environments require protective
coatings to extend their lifetime and reliability. Although transition metal nitrides possess …
coatings to extend their lifetime and reliability. Although transition metal nitrides possess …