The use of a bifunctional cinchona/thiourea organocatalyst for the direct and α-
stereoselective glycosylation of 2-nitrogalactals is demonstrated for the first time. The …

Glycosylations of 4, 6-tethered glucosazide donors with a panel of model acceptors revealed
the effect of acceptor nucleophilicity on the stereoselectivity of these donors. The differences …

The first enantioselective total synthesis of fidaxomicin, also known as tiacumicin B or
lipiarmycin A3, is reported. This novel glycosylated macrolide antibiotic is used in the clinic …

Glycosylation reaction is an important class of reactions in organic chemistry, and the
development of the method contributes to the synthesis of many biologically active …

Описан синтез серии гликозил-доноров с галогенбензоильными заместителями при
атомах O (4) и O (6). Изучено поведение синтезированных гликозил-доноров в реакции …