Inferring the Molecular Basis for Dissolved Organic Matter Photochemical and Optical Properties

S Buckley, G McKay, F Leresche… - … Science & Technology, 2024 - ACS Publications
Despite the widespread use of photochemical and optical properties to characterize
dissolved organic matter (DOM), a significant gap persists in our understanding of the …

Role of direct and sensitized photolysis in the photomineralization of dissolved organic matter and model chromophores to carbon dioxide

S Buckley, F Leresche, K Norris… - … Science & Technology, 2024 - ACS Publications
This study addresses the fundamental processes that drive the photomineralization of
dissolved organic matter (DOM) to carbon dioxide (CO2), deconvoluting the role of direct …

Evaluating the pH-dependence of DOM absorbance, fluorescence, and photochemical production of singlet oxygen

A Allen, K Cheng, G McKay - Environmental Science: Processes & …, 2023 - pubs.rsc.org
The protonation state of dissolved organic matter (DOM) impacts its structure and function in
natural and engineered environmental systems, including DOM's ability to absorb light and …

Evaluation of CESM1 (WACCM) free-running and specified dynamics atmospheric composition simulations using global multispecies satellite data records

L Froidevaux, DE Kinnison, R Wang… - Atmospheric …, 2019 - acp.copernicus.org
We have analyzed near-global stratospheric data (and mesospheric data as well for H 2 O)
in terms of absolute abundances, variability, and trends for O 3, H 2 O, HCl, N 2 O, and HNO …

Highly selective in-situ generation of 1O2 via electronic structure regulation of single atom sites in electro-Fenton system

QQ Tang, BX Wu, XW Huang, Y Hu, D Hou… - Applied Catalysis B …, 2025 - Elsevier
Highly selective generation of singlet oxygen (1 O 2) in the electro-Fenton system remains
challenging due to susceptibility of the OO bond to break in O 2 reduction reaction and …

Seasonal variations in photooxidant formation and light absorption in aqueous extracts of ambient particles

L Ma, R Worland, L Heinlein, C Guzman… - Atmospheric …, 2024 - acp.copernicus.org
Fog/cloud drops and aerosol liquid water are important sites for the transformations of
atmospheric species, largely through reactions with photoformed oxidants such as the …

Mechanistic insight into multiple effects of copper ion on the photoreactivity of dissolved organic matter

Z Li, H Zhao, J Lv, S Azam - Journal of Hazardous Materials, 2025 - Elsevier
Sunlight irradiation of dissolved organic matter (DOM) in surface water results in the
production of photochemically produced reactive intermediates (PPRIs). This process is …

Characterization of Natural Organic Matter and Humic Substance Isolates by Size Exclusion Chromatography following Reduction with Sodium Borohydride

H Li, B Hanson, G McKay - ACS Environmental Au, 2024 - ACS Publications
Chemical reduction with sodium borohydride has been used for over four decades to probe
the presence and function of carbonyl-containing moieties in dissolved organic matter …

Promotion effect of foam formation on the degradation of polyvinyl alcohol by ozone microbubble

L Zhang, P Li, X Wang, X He, E Li, Q Lan, Y Liu… - Journal of Environmental …, 2023 - Elsevier
Polyvinyl alcohol (PVA), extensively utilized in diverse industries, presents a challenge in
terms of degradation. The combination of ozone (O 3) with microbubbles enhances ozone's …

Optical properties and photobleaching of wildfire ashes aqueous extracts

F Leresche, SJ Fischer, S Buckley… - … Science: Processes & …, 2025 - pubs.rsc.org
Wildfires can severely degrade soils and watersheds. Post-fire rain events can leach ashes
and altered dissolved organic matter (DOM) into streams, impacting water quality and …