Secondary building units as the turning point in the development of the reticular chemistry of MOFs

MJ Kalmutzki, N Hanikel, OM Yaghi - Science advances, 2018 - science.org
The secondary building unit (SBU) approach was a turning point in the discovery of
permanently porous metal-organic frameworks (MOFs) and in launching the field of reticular …

A review on molten salt synthesis of metal oxide nanomaterials: Status, opportunity, and challenge

SK Gupta, Y Mao - Progress in Materials Science, 2021 - Elsevier
Molten-salt synthesis (MSS) method becomes an excellent bottom-up synthesis technique of
nanomaterials with various chemical compositions and morphologies because of its …

The thermodynamic scale of inorganic crystalline metastability

W Sun, ST Dacek, SP Ong, G Hautier, A Jain… - Science …, 2016 - science.org
The space of metastable materials offers promising new design opportunities for next-
generation technological materials, such as complex oxides, semiconductors …

Hydrogen-substituted graphdiyne-assisted ultrafast sparking synthesis of metastable nanomaterials

X Zheng, X Gao, RA Vilá, Y Jiang, J Wang, R Xu… - Nature …, 2023 - nature.com
Metastable nanomaterials, such as single-atom and high-entropy systems, with exciting
physical and chemical properties are increasingly important for next-generation …

The interplay between thermodynamics and kinetics in the solid-state synthesis of layered oxides

M Bianchini, J Wang, RJ Clément, B Ouyang, P **ao… - Nature materials, 2020 - nature.com
In the synthesis of inorganic materials, reactions often yield non-equilibrium kinetic
byproducts instead of the thermodynamic equilibrium phase. Understanding the competition …

Fluorine-free fabrication of MXene via photo-fenton approach for advanced lithium–sulfur batteries

L Liang, L Niu, T Wu, D Zhou, Z **ao - ACS nano, 2022 - ACS Publications
The mainstream synthesis method for MXene is using aqueous fluorine-containing acidic
solutions to eliminate the A-element layers from their MAX phases. However, this strategy is …

Topochemical deintercalation of Al from MoAlB: stepwise etching pathway, layered intergrowth structures, and two-dimensional MBene

LT Alameda, P Moradifar, ZP Metzger… - Journal of the …, 2018 - ACS Publications
The synthesis of refractory materials usually relies on high-temperature conditions to drive
diffusion-limited solid-state reactions. These reactions result in thermodynamically stable …

Perspective on intermetallics towards efficient electrocatalytic water-splitting

C Walter, PW Menezes, M Driess - Chemical Science, 2021 - pubs.rsc.org
Intermetallic compounds exhibit attractive electronic, physical, and chemical properties,
especially in terms of a high density of active sites and enhanced conductivity, making them …

Zeolite-like metal–organic frameworks (ZMOFs): design, synthesis, and properties

M Eddaoudi, DF Sava, JF Eubank, K Adil… - Chemical Society …, 2015 - pubs.rsc.org
This review highlights various design and synthesis approaches toward the construction of
ZMOFs, which are metal–organic frameworks (MOFs) with topologies and, in some cases …

Luminescent functional metal–organic frameworks

Y Cui, Y Yue, G Qian, B Chen - Chemical reviews, 2012 - ACS Publications
Traditional inorganic and organic luminescent materials have been extensively explored
and realized for their diverse functionalities and applications in lighting, display, sensing …