Computational approach to molecular catalysis by 3d transition metals: challenges and opportunities

KD Vogiatzis, MV Polynski, JK Kirkland… - Chemical …, 2018 - ACS Publications
Computational chemistry provides a versatile toolbox for studying mechanistic details of
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …

Accuracy and interpretability: The devil and the holy grail. New routes across old boundaries in computational spectroscopy

C Puzzarini, J Bloino, N Tasinato, V Barone - Chemical reviews, 2019 - ACS Publications
The past decade has witnessed an increasing interaction between experiment and theory in
the field of molecular spectroscopy. On the computational side, ongoing developments of …

[HTML][HTML] CP2K: An electronic structure and molecular dynamics software package-Quickstep: Efficient and accurate electronic structure calculations

TD Kühne, M Iannuzzi, M Del Ben, VV Rybkin… - The Journal of …, 2020 - pubs.aip.org
CP2K is an open source electronic structure and molecular dynamics software package to
perform atomistic simulations of solid-state, liquid, molecular, and biological systems. It is …

Atomistic modeling of electrocatalysis: Are we there yet?

N Abidi, KRG Lim, ZW Seh… - Wiley Interdisciplinary …, 2021 - Wiley Online Library
Electrified interfaces play a prime role in energy technologies, from batteries and capacitors
to heterogeneous electrocatalysis. The atomistic understanding and modeling of these …

Molecular structure and modeling of water–air and ice–air interfaces monitored by sum-frequency generation

F Tang, T Ohto, S Sun, JR Rouxel, S Imoto… - Chemical …, 2020 - ACS Publications
From a glass of water to glaciers in Antarctica, water–air and ice–air interfaces are abundant
on Earth. Molecular-level structure and dynamics at these interfaces are key for …

Raman spectrum and polarizability of liquid water from deep neural networks

GM Sommers, MFC Andrade, L Zhang… - Physical Chemistry …, 2020 - pubs.rsc.org
We introduce a scheme based on machine learning and deep neural networks to model the
environmental dependence of the electronic polarizability in insulating materials. Application …

Theoretical insights into the surface physics and chemistry of redox-active oxides

R Rousseau, VA Glezakou, A Selloni - Nature Reviews Materials, 2020 - nature.com
Redox-active oxides find use in many applications, including catalysts, photovoltaic devices,
self-cleaning glasses, chemical sensors and electronic components. Their utility derives …

Vibrational spectroscopy by means of first‐principles molecular dynamics simulations

E Ditler, S Luber - Wiley Interdisciplinary Reviews …, 2022 - Wiley Online Library
Vibrational spectroscopy is one of the most important experimental techniques for the
characterization of molecules and materials. Spectroscopic signatures retrieved in …

[HTML][HTML] Perspective: Multireference coupled cluster theories of dynamical electron correlation

FA Evangelista - The Journal of Chemical Physics, 2018 - pubs.aip.org
Predicting the electronic structure and properties of molecular systems that display strong
electron correlation effects continues to remain a fundamental theoretical challenge. This …

Application of quantum mechanics/molecular mechanics methods in the study of enzymatic reaction mechanisms

SF Sousa, AJM Ribeiro, RPP Neves… - Wiley …, 2017 - Wiley Online Library
Quantum mechanics/molecular mechanics (QM/MM) methods offer a very appealing option
for the computational study of enzymatic reaction mechanisms, by separating the problem …