Using microemulsions: formulation based on knowledge of their mesostructure

M Gradzielski, M Duvail, PM de Molina… - Chemical …, 2021 - ACS Publications
Microemulsions, as thermodynamically stable mixtures of oil, water, and surfactant, are
known and have been studied for more than 70 years. However, even today there are still …

Rare earth elements: Mendeleev's bane, modern marvels

T Cheisson, EJ Schelter - Science, 2019 - science.org
The rare earths (REs) are a family of 17 elements that exhibit pronounced chemical
similarities as a group, while individually expressing distinctive and varied electronic …

Elucidating the speciation of extracted lanthanides by diglycolamides

AA Peroutka, SS Galley, JC Shafer - Coordination Chemistry Reviews, 2023 - Elsevier
Many studies over the past few decades have been devoted to addressing the application of
diglycolamides (DGAs) for hydrometallurgical-based, f-element separations. Work to date …

Molecular forces in liquid–liquid extraction

M Špadina, JF Dufrêche, S Pellet-Rostaing… - Langmuir, 2021 - ACS Publications
The phase transfer of ions is driven by gradients of chemical potentials rather than
concentrations alone (ie, by both the molecular forces and entropy). Extraction is a …

Microfluidic lab-on-chip advances for liquid–liquid extraction process studies

A Maurice, J Theisen, JCP Gabriel - Current Opinion in Colloid & Interface …, 2020 - Elsevier
The ever-increasing complexity of industrial product recycling calls for more efficient
purification processes such as liquid–liquid (L/L) extraction. Because of the high complexity …

Synergistic solvent extraction is driven by entropy

M Špadina, K Bohinc, T Zemb, JF Dufrêche - ACS nano, 2019 - ACS Publications
In solvent extraction, the self-assembly of amphiphilic molecules into an organized structure
is the phenomenon responsible for the transfer of the metal ion from the aqueous phase to …

Importance of weak interactions in the formulation of organic phases for efficient liquid/liquid extraction of metals

D Bourgeois, A El Maangar, S Dourdain - Current Opinion in Colloid & …, 2020 - Elsevier
Recent experimental studies demonstrate the need to take into account weak interactions in
the understanding of solvent extraction processes. This well-established industrial …

Molecular Dynamics Study of the Aggregation Behavior of N,N,N′,N′-Tetraoctyl Diglycolamide

D Massey, A Masters, J Macdonald-Taylor… - The Journal of …, 2022 - ACS Publications
Liquid–liquid extraction is a commonly used technique to separate metals and is a process
that has particular relevance to the nuclear industry. There has been a drive to use …

A telesco** view of solute architectures in a complex fluid system

R Motokawa, T Kobayashi, H Endo, J Mu… - ACS central …, 2018 - ACS Publications
Short-and long-range correlations between solutes in solvents can influence the
macroscopic chemistry and physical properties of solutions in ways that are not fully …

Origins of clustering of metalate–extractant complexes in liquid–liquid extraction

S Nayak, RR Kumal, Z Liu, B Qiao… - … Applied Materials & …, 2021 - ACS Publications
Effective and energy-efficient separation of precious and rare metals is very important for a
variety of advanced technologies. Liquid–liquid extraction (LLE) is a relatively less energy …