Using microemulsions: formulation based on knowledge of their mesostructure
Microemulsions, as thermodynamically stable mixtures of oil, water, and surfactant, are
known and have been studied for more than 70 years. However, even today there are still …
known and have been studied for more than 70 years. However, even today there are still …
Rare earth elements: Mendeleev's bane, modern marvels
The rare earths (REs) are a family of 17 elements that exhibit pronounced chemical
similarities as a group, while individually expressing distinctive and varied electronic …
similarities as a group, while individually expressing distinctive and varied electronic …
Elucidating the speciation of extracted lanthanides by diglycolamides
Many studies over the past few decades have been devoted to addressing the application of
diglycolamides (DGAs) for hydrometallurgical-based, f-element separations. Work to date …
diglycolamides (DGAs) for hydrometallurgical-based, f-element separations. Work to date …
Molecular forces in liquid–liquid extraction
The phase transfer of ions is driven by gradients of chemical potentials rather than
concentrations alone (ie, by both the molecular forces and entropy). Extraction is a …
concentrations alone (ie, by both the molecular forces and entropy). Extraction is a …
Microfluidic lab-on-chip advances for liquid–liquid extraction process studies
The ever-increasing complexity of industrial product recycling calls for more efficient
purification processes such as liquid–liquid (L/L) extraction. Because of the high complexity …
purification processes such as liquid–liquid (L/L) extraction. Because of the high complexity …
Synergistic solvent extraction is driven by entropy
In solvent extraction, the self-assembly of amphiphilic molecules into an organized structure
is the phenomenon responsible for the transfer of the metal ion from the aqueous phase to …
is the phenomenon responsible for the transfer of the metal ion from the aqueous phase to …
Importance of weak interactions in the formulation of organic phases for efficient liquid/liquid extraction of metals
D Bourgeois, A El Maangar, S Dourdain - Current Opinion in Colloid & …, 2020 - Elsevier
Recent experimental studies demonstrate the need to take into account weak interactions in
the understanding of solvent extraction processes. This well-established industrial …
the understanding of solvent extraction processes. This well-established industrial …
Molecular Dynamics Study of the Aggregation Behavior of N,N,N′,N′-Tetraoctyl Diglycolamide
D Massey, A Masters, J Macdonald-Taylor… - The Journal of …, 2022 - ACS Publications
Liquid–liquid extraction is a commonly used technique to separate metals and is a process
that has particular relevance to the nuclear industry. There has been a drive to use …
that has particular relevance to the nuclear industry. There has been a drive to use …
A telesco** view of solute architectures in a complex fluid system
R Motokawa, T Kobayashi, H Endo, J Mu… - ACS central …, 2018 - ACS Publications
Short-and long-range correlations between solutes in solvents can influence the
macroscopic chemistry and physical properties of solutions in ways that are not fully …
macroscopic chemistry and physical properties of solutions in ways that are not fully …
Origins of clustering of metalate–extractant complexes in liquid–liquid extraction
Effective and energy-efficient separation of precious and rare metals is very important for a
variety of advanced technologies. Liquid–liquid extraction (LLE) is a relatively less energy …
variety of advanced technologies. Liquid–liquid extraction (LLE) is a relatively less energy …