Phosphines as building blocks in coordination-based self-assembly

SL James - Chemical Society Reviews, 2009 - pubs.rsc.org
Although phosphines have been less widely investigated in coordination self-assembly than
have N-and O-donor ligands, interesting and unusual chemistry has been observed from …

Supramolecular architectures and magnetic behavior of coordination polymers from copper (II) carboxylates and 1, 2-bis (4-pyridyl) ethane as a flexible bridging …

R Carballo, B Covelo, MS El Fallah, J Ribas… - Crystal growth & …, 2007 - ACS Publications
The combination of the flexible bpetha ligand with different copper (II) carboxylates in a 1: 1
molar ratio leads to the formation by self-assembly of three new one-dimensional (1D) …

Role of inorganic and organic anions in the formation of metallosupramolecular assemblies of silver (I) coordination polymers with the twisted ligand bis (4-pyridylthio) …

R Carballo, B Covelo, E García-Martínez, AB Lago… - Polyhedron, 2009 - Elsevier
Reaction of the twisted pyridyl dithioether ligand bis (4-pyridylthio) methane (4bpytm) with
silver (I) salts afforded four complexes with 1: 1 stoichiometries, namely [Ag …

Synthesis and structure of indenyl rhodium (I) complexes containing unsaturated phosphines: catalyst precursors for alkene hydroboration

CN Garon, DI McIsaac, CM Vogels, A Decken… - Dalton …, 2009 - pubs.rsc.org
The indenyl compound (η5-C9H7) Rh (coe) 2 (1, coe= cis-cyclooctene) has been prepared
as a thermally stable alternative to the diethylene derivative (η5-C9H7) Rh (η2-H2CCH2) 2 …

Ir (I)–carbonyl complexes of coumarinazoimidazoles: Synthesis structure, electrochemistry, photophysical properties and DFT calculations

P Datta, D Sardar, P Mitra, C Sinha - Polyhedron, 2011 - Elsevier
The reactions of Vaska's complex [IrCl (CO)(PPh 3) 2] with 2-(coumaryl-6-azo) imidazole (CZ-
H) and its derivatives (CZ-X) have synthesized [Ir (CZ)(CO)(PPh 3) 2] and [Ir (CZ-X)(CO)(PPh …

Bis (diphenylphosphino) acetylene-bridged ten-membered dimetallacyclic Cu (I) complexes: 2, 2′-bipyridine methyl substitution effect on structure and bonding

A Fazal, B El Ali, L Ouahab, M Fettouhi - Polyhedron, 2013 - Elsevier
Four new bis (diphenylphosphino) acetylene-bridged copper (I) bipyridine complexes,[Cu2
(dppa) 2 (L) 2](BF4) 2; L= 2, 2′-bipyridine (1), 4, 4′-dimethyl-2, 2′-bipyridine (2), 5, 5 …

Anion effect on the construction of copper (II) coordination polymers with the twisted ligand bis (4-pyridylthio) methane

R Carballo, B Covelo, N Fernández-Hermida… - Polyhedron, 2008 - Elsevier
The reaction of CuSO4· H2O with 4-bpytm [4-bpytm= bis (4-pyridylthio) methane] in EtOH
afforded the complex [Cu (SO4)(4-bpytm)(H2O) 3]· H2O (1· H2O) while the reaction of 4 …

Synthesis and Solid-State Behavior of Host–Guest Carbonyl Rh (I) Polymers Assembled through Bidentate Phosphine Ligands

N Janjic, G Peli, L Garlaschelli, A Sironi… - Crystal Growth and …, 2008 - ACS Publications
The self-assembly of Rh (I) carbonyl and bis (diphenylphosphino) hexane (dpphex) ligands
yields polymers with the general formula [RhCl (CO)(dpphex)]∞, obtained in two crystalline …

Bimetallic bis (diphenylphosphino) acetylene bridged copper (I) complexes with 1, 10-phenanthroline derivatives: synthesis, crystal structure, and spectroscopic …

A Fazal, A Al-Dawsari, B El Ali, L Ouahab… - Journal of …, 2014 - Taylor & Francis
A new series of bimetallic bis (diphenylphosphino) acetylene-bridged copper (I) 1, 10-
phenanthroline complexes,[Cu2 (dppa) 2 (L) 2](BF4) 2; L= 1, 10-phenanthroline (1); 4 …

Phosphine Acetylenic Macrocycles and Cages: Synthesis and Reactivity

W Weymiens, JC Slootweg, K Lammertsma - … : Advanced Tools in Catalysis …, 2011 - Springer
The syntheses, structural properties, and reactivities are reviewed for phosphine-acetylenic
macrocycles and cages. These compounds are of current interest for their phosphorus …