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Molecular photoswitches in aqueous environments
Molecular photoswitches enable dynamic control of processes with high spatiotemporal
precision, using light as external stimulus, and hence are ideal tools for different research …
precision, using light as external stimulus, and hence are ideal tools for different research …
Visible light-responsive materials: the (photo) chemistry and applications of donor–acceptor Stenhouse adducts in polymer science
Donor–acceptor Stenhouse adduct (DASA) photoswitches have gained a lot of attention
since their discovery in 2014. Their negative photochromism, visible light absorbance …
since their discovery in 2014. Their negative photochromism, visible light absorbance …
Nonlinear optical responses of photoswitchable donor–acceptor Stenhouse adducts
This work combines hyper-Rayleigh scattering (HRS) experiments performed in the NIR
range (1.30 and 1.60 μm) and quantum chemical calculations to provide a comprehensive …
range (1.30 and 1.60 μm) and quantum chemical calculations to provide a comprehensive …
A multi-stage single photochrome system for controlled photoswitching responses
The ability of molecular photoswitches to convert on/off responses into large macroscale
property change is fundamental to light-responsive materials. However, moving beyond …
property change is fundamental to light-responsive materials. However, moving beyond …
Robust, Ultrafast and Reversible Photoswitching in Bulk Polymers Enabled by Octupolar Molecule Design
L Fang, Z Lin, Y Zhang, B Ye, J Li, Q Ran… - Angewandte …, 2024 - Wiley Online Library
Improving the photoswitching rate and robustness of photochromic molecules in bulk solids
is paramount for practical applications but remains an on‐going challenge. Here, we …
is paramount for practical applications but remains an on‐going challenge. Here, we …
Enhanced sampling aided design of molecular photoswitches
Advances in the evolving field of atomistic simulations promise important insights for the
design and fundamental understanding of novel molecular photoswitches. Here, we use …
design and fundamental understanding of novel molecular photoswitches. Here, we use …
Compartmentalizing Donor–Acceptor Stenhouse Adducts for Structure–Property Relationship Analysis
CA Reyes, A Karr, CA Ramsperger, ATG K… - Journal of the …, 2024 - ACS Publications
The development of photoswitches that absorb low energy light is of notable interest due to
the growing demand for smart materials and therapeutics necessitating benign stimuli …
the growing demand for smart materials and therapeutics necessitating benign stimuli …
Donor–acceptor Stenhouse adducts: exploring the effects of ionic character
The effects of solution‐state dielectric and intermolecular interactions on the degree of
charge separation provide a route to understanding the switching properties and …
charge separation provide a route to understanding the switching properties and …
In silico discovery of multistep chemistry initiated by a conical intersection: the challenging case of donor–acceptor Stenhouse adducts
Detailed mechanistic understanding of multistep chemical reactions triggered by internal
conversion via a conical intersection is a challenging task that emphasizes limitations in …
conversion via a conical intersection is a challenging task that emphasizes limitations in …
Ester matters? Promoting photoisomerization of donor–acceptor Stenhouse adducts in the solid state and “burn after reading” encryption
Striking towards secret leakage is the key challenge in information encryption. In this work,
we reported a “burn after reading” secrecy system based on the reversible …
we reported a “burn after reading” secrecy system based on the reversible …