1.1. General Considerations Palladium catalysis is one of the most important synthetic tools
in modern organic synthesis. A particularly attractive synthetic feature of palladium catalysis …

The chemistry of alcohols occupies a central place in organic synthesis. Recently, we
reviewed the palladiumcatalysed oxidations of primary and secondary alcohols into their …

An aqueous biphasic reaction system enables the direct use of allyl alcohol in the Tsuji−
Trost reaction without the help of any activating reagents for allyl alcohol. The reaction …

Organoselenium ligands are building blocks of several transition metal complexes which
catalyze various organic reactions efficiently in solution. In this review the survey of …

Electrophilic allylic substitution of allylstannanes with aldehyde and imine substrates could
be achieved by employment of palladium pincer complex catalysts. It was found that the …

New easily accessible 1, 1 '-bi-2-naphthol-(BINOL-) and biphenanthrol-based chiral pincer
complex catalysts were prepared for selective (up to 85% enantiomeric excess) allylation of …

The palladium‐catalyzed intramolecular coupling of allyl stannanes with allyl carboxylates
provides a general synthesis of five‐and six‐membered‐ring carbocycles. The …

Herein we report a Pd‐catalyzed dearomative methoxyallylation of 3‐nitroindoles with
readily available allyl carbonates. Good yields (up to 86%) and diastereoselectivity (up to> …

This thesis is focused on investigation of the structure, reactivity and isomerization reactions
of η1-allylpalladium complexes, which are key intermediates in catalytic transformations …

Palladium pincer complex 1 catalyzes the reaction of trifluoro (allyl) borate 2 with a wide
range of tosylimines (3) under mild and neutral reaction conditions. This catalytic …