[HTML][HTML] Microwave-assisted synthesis: Can transition metal complexes take advantage of this “Green” method?

E Gabano, M Ravera - Molecules, 2022 - mdpi.com
Microwave-assisted synthesis is considered environmental-friendly and, therefore, in
agreement with the principles of green chemistry. This form of energy has been employed …

Alternative technologies that facilitate access to discrete metal complexes

A Beillard, X Bantreil, TX Métro, J Martinez… - Chemical …, 2019 - ACS Publications
Organometallic complexes: these two words jump to the mind of the chemist and are directly
associated with their utility in catalysis or as a pharmaceutical. Nevertheless, to be able to …

[SÁCH][B] Microwave heating as a tool for sustainable chemistry

NE Leadbeater - 2010 - taylorfrancis.com
Shorter reaction times, higher product yields, and enhanced selectivity are some of the
advantages microwave heating has over conventional methods, causing its use to transition …

Novel metal-mediated (M= Pd, Pt) coupling between isonitriles and benzophenone hydrazone as a route to aminocarbene complexes exhibiting high catalytic activity …

KV Luzyanin, AG Tskhovrebov, MC Carias… - …, 2009 - ACS Publications
Metal-mediated reaction between equimolar amounts of cis-[MCl2 (C NR) 2][M= Pd, R=
cyclohexyl (Cy) 1, t Bu 2, 2, 6-Me2C6H3 (Xyl) 3, 4-MeOC6H4 4; M= Pt, R= cyclohexyl (Cy) 5 …

1, 3-Dipolar cycloaddition of nitrone-type dipoles to uncomplexed and metal-bound substrates bearing the CN triple bond

NA Bokach, ML Kuznetsov, VY Kukushkin - Coordination Chemistry …, 2011 - Elsevier
Metal-free and metal-mediated routes for 1, 3-dipolar cycloaddition of nitrone-type dipoles to
substrates bearing the CN triple bond are compared and the reactions are categorized. In 1 …

Synthesis, X-ray, Hirshfeld combined with DFT, anticancer effects with molecular docking confirmation of (E)-4-cyanobenzaldehyde oxime and (Z)–N-methyl-C-4 …

J Lasri, SM Soliman, EMM Ali, NE Eltayeb… - Journal of Molecular …, 2024 - Elsevier
Abstract (E)-4-cyanobenzaldehyde oxime 1 and (Z)–N-methyl-C-4-substituted phenyl
aldonitrones 2 and 3 were synthesised and fully characterised. With the help of Hirshfeld …

Coupling between 3-iminoisoindolin-1-ones and complexed isonitriles as a metal-mediated route to a novel type of palladium and platinum iminocarbene species

KV Luzyanin, AJL Pombeiro, M Haukka… - …, 2008 - ACS Publications
The reaction between isonitrile in cis-[MCl2 (C NR) 2][M= Pd, R= Cy 1, Bu t 2, C6H3 (2, 6-
Me2) 3; M= Pt, R= Cy 4, Bu t 5, C6H3 (2, 6-Me2) 6] and various unsubstituted or substituted …

Oxadiazoline and ketoimine palladium (II) complexes supported on a chitosan membrane and their catalytic activity for the microwave-assisted Suzuki–Miyaura cross …

J Lasri, TCO Mac Leod, AJL Pombeiro - Applied Catalysis A: General, 2011 - Elsevier
The fused bicyclic Δ4-1, 2, 4-oxadiazoline trans-() palladium (II) complex 1 (R= p-ClC6H4),
in refluxing chloroform, undergoes N–O bond cleavage of the oxadiazoline ring to furnish …

Metal‐mediated [2+ 3] cycloaddition of nitrones to palladium‐bound isonitriles

KV Luzyanin, AG Tskhovrebov… - … A European Journal, 2009 - Wiley Online Library
Cycloadditions! The metal‐mediated [2+ 3] cycloaddition of acyclic [− O+ N (R2)(H) R3]
and nonaromatic cyclic nitrones [− O+ Na CHCH2CH2CbMe2 (Na Cb)] to palladium …

Single-pot template transformations of cyanopyridines on a Pd II centre: syntheses of ketoimine and 2, 4-dipyridyl-1, 3, 5-triazapentadiene palladium (II) complexes …

MN Kopylovich, J Lasri, MFCG da Silva… - Dalton …, 2009 - pubs.rsc.org
[2+ 3] cycloaddition of the pyrrolin N-oxide− O+ NCHCH2CH2CMe22 with 2-cyanopyridine
NC5H4 (2-CN) 1a in the presence of PdCl2 at room temperature in acetone gives the …