Ethylene as a synthon in carbonylative synthesis

JX Xu, Y Yuan, XF Wu - Coordination Chemistry Reviews, 2023 - Elsevier
We summarized and discussed the main achievements on transitional metal-catalyzed
carbonylative transformations of ethylene in this review. Various bulk compounds and also …

Current state of the art of the solid Rh-based catalyzed hydroformylation of short-chain olefins

S Hanf, L Alvarado Rupflin, R Gläser, SA Schunk - Catalysts, 2020 - mdpi.com
The hydroformylation of olefins is one of the most important homogeneously catalyzed
processes in industry to produce bulk chemicals. Despite the high catalytic activities and …

Atomic-level insights in optimizing reaction paths for hydroformylation reaction over Rh/CoO single-atom catalyst

L Wang, W Zhang, S Wang, Z Gao, Z Luo… - Nature …, 2016 - nature.com
Rh-based heterogeneous catalysts generally have limited selectivity relative to their
homogeneous counterparts in hydroformylation reactions despite of the convenience of …

Active and regioselective Ru single-site heterogeneous catalysts for alpha-olefin hydroformylation

FJ Escobar-Bedia, M Lopez-Haro, JJ Calvino… - ACS …, 2022 - ACS Publications
A heterogeneous ruthenium catalyst consisting of isolated single atoms and disordered
clusters stabilized in a N-doped carbon matrix has been synthesized with very good activity …

Suppressing Metal Leaching and Sintering in Hydroformylation Reaction by Modulating the Coordination of Rh Single Atoms with Reactants

Z Yu, S Zhang, L Zhang, X Liu, Z Jia, L Li… - Journal of the …, 2024 - ACS Publications
Hydroformylation reaction is one of the largest homogeneously catalyzed industrial
processes yet suffers from difficulty and high cost in catalyst separation and recovery …

Single atom dispersed Rh-biphephos&PPh 3@ porous organic copolymers: highly efficient catalysts for continuous fixed-bed hydroformylation of propene

C Li, L Yan, L Lu, K **ong, W Wang, M Jiang, J Liu… - Green …, 2016 - pubs.rsc.org
A vinyl functionalized biphephos ligand with high steric hindrance was copolymerized with
tris (4-vinphenyl) phosphane and other ligands to afford efficient porous organic copolymers …

A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts

C Li, W Wang, L Yan, Y Ding - Frontiers of Chemical Science and …, 2018 - Springer
Hydroformylation has been widely used in industry to manufacture high value-added
aldehydes and alcohols, and is considered as the largest homogenously catalyzed process …

Construction of Rh-N4 single atoms and Rh clusters dual-active sites for synergistic heterogeneous hydroformylation of olefins with ultra-high turnover frequency

D Yang, S Tao, H Zhu, Z Wang, W Gao, J Yu… - Chemical Engineering …, 2024 - Elsevier
The design and construction of Rh-based heterogeneous catalysts with excellent catalytic
activity and high atom utilization for hydroformylation of olefins is extremely important but still …

Heterogeneous Rh/CPOL-BP&P (OPh) 3 catalysts for hydroformylation of 1-butene: the formation and evolution of the active species

Y Wang, L Yan, C Li, M Jiang, Z Zhao, G Hou, Y Ding - Journal of Catalysis, 2018 - Elsevier
Porous organic copolymer (designated as CPOL-BP&P (OPh) 3) containing vinyl biphephos
moieties and tris (4-vinylphenyl) phosphite (P (OPh) 3) moieties was synthesized through a …

Xantphos doped Rh/POPs-PPh3 catalyst for highly selective long-chain olefins hydroformylation: Chemical and DFT insights into Rh location and the roles of …

C Li, K Sun, W Wang, L Yan, X Sun, Y Wang, K **ong… - Journal of …, 2017 - Elsevier
Vinyl functionalized Xantphos ligand (denoted as 4v-Xantphos) was newly synthesized and
successfully doped into the PPh 3 based porous organic polymers (POPs) through the …