Rhodium-catalyzed asymmetric C–H functionalization reactions
CX Liu, SY Yin, F Zhao, H Yang, Z Feng, Q Gu… - Chemical …, 2023 - ACS Publications
This review summarizes the advancements in rhodium-catalyzed asymmetric C–H
functionalization reactions during the last two decades. Parallel to the rapidly developed …
functionalization reactions during the last two decades. Parallel to the rapidly developed …
Electrochemical late-stage functionalization
Late-stage functionalization (LSF) constitutes a powerful strategy for the assembly or
diversification of novel molecular entities with improved physicochemical or biological …
diversification of novel molecular entities with improved physicochemical or biological …
Enantioselective electrochemical cobalt-catalyzed aryl C–H activation reactions
Enantioselective redox transformations typically rely on costly transition metals as catalysts
and often stoichiometric amounts of chemical redox agents as well. Electrocatalysis …
and often stoichiometric amounts of chemical redox agents as well. Electrocatalysis …
An atomically dispersed Mn-photocatalyst for generating hydrogen peroxide from seawater via the water oxidation reaction (WOR)
In this work, we have fabricated an aryl amino-substituted graphitic carbon nitride (g-C3N4)
catalyst with atomically dispersed Mn capable of generating hydrogen peroxide (H2O2) …
catalyst with atomically dispersed Mn capable of generating hydrogen peroxide (H2O2) …
Transition-Metal-Catalyzed, Coordination-Assisted Functionalization of Nonactivated C(sp3)–H Bonds
Transition-metal-catalyzed, coordination-assisted C (sp3)–H functionalization has
revolutionized synthetic planning over the past few decades as the use of these directing …
revolutionized synthetic planning over the past few decades as the use of these directing …
Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII
Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …
valence electron configurations have outstanding photophysical and photochemical …
Late-stage C–H functionalization offers new opportunities in drug discovery
Over the past decade, the landscape of molecular synthesis has gained major impetus by
the introduction of late-stage functionalization (LSF) methodologies. C–H functionalization …
the introduction of late-stage functionalization (LSF) methodologies. C–H functionalization …
Late-stage functionalization for improving drug-like molecular properties
The development of late-stage functionalization (LSF) methodologies, particularly C–H
functionalization, has revolutionized the field of organic synthesis. Over the past decade …
functionalization, has revolutionized the field of organic synthesis. Over the past decade …
C–H activation
Transition metal-catalysed C–H activation has emerged as an increasingly powerful platform
for molecular syntheses, enabling applications to natural product syntheses, late-stage …
for molecular syntheses, enabling applications to natural product syntheses, late-stage …
Recent advances in transition-metal-catalyzed carbene insertion to C–H bonds
Y He, Z Huang, K Wu, J Ma, YG Zhou… - Chemical Society Reviews, 2022 - pubs.rsc.org
C–H functionalization has been emerging as a powerful method to establish carbon–carbon
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …