Molecular ratchets and kinetic asymmetry: Giving chemistry direction
Over the last two decades ratchet mechanisms have transformed the understanding and
design of stochastic molecular systems—biological, chemical and physical—in a move away …
design of stochastic molecular systems—biological, chemical and physical—in a move away …
Artificial molecular pumps
Reflecting on recent progress in bottom-up engineering focused on creating the smallest
devices capable of controlling nanoscale motion, artificial molecular pumps (AMPs) are …
devices capable of controlling nanoscale motion, artificial molecular pumps (AMPs) are …
Photoswitchable Imines Drive Dynamic Covalent Systems to Nonequilibrium Steady States
Coupling a photochemical reaction to a thermal exchange process can drive the latter to a
nonequilibrium steady state (NESS) under photoirradiation. Typically, systems use separate …
nonequilibrium steady state (NESS) under photoirradiation. Typically, systems use separate …
The sugar cube: Network control and emergence in stereoediting reactions
Stereochemical editing strategies have recently enabled the transformation of readily
accessible substrates into rare and valuable products. Typically, site selectivity is achieved …
accessible substrates into rare and valuable products. Typically, site selectivity is achieved …
Physicochemical Principles of AC Electrosynthesis: Reversible Reactions
Electrolysis integrates renewable energy into chemical manufacturing and is key to
sustainable chemistry. Controlling the waveform beyond direct current (DC) addresses the …
sustainable chemistry. Controlling the waveform beyond direct current (DC) addresses the …
Catalytic resonance theory: the catalytic mechanics of programmable ratchets
Catalytic reaction networks of multiple elementary steps operating under dynamic conditions
via a programmed input oscillation are difficult to interpret and optimize due to reaction …
via a programmed input oscillation are difficult to interpret and optimize due to reaction …
A Minimalistic Covalent Bond‐Forming Chemical Reaction Cycle that Consumes Adenosine Diphosphate
T Marchetti, BMW Roberts, D Frezzato… - Angewandte …, 2024 - Wiley Online Library
The development of synthetic active matter requires the ability to design materials capable of
harnessing energy from a source to carry out work. Nature achieves this using chemical …
harnessing energy from a source to carry out work. Nature achieves this using chemical …
Dynamic Promotion of the Oxygen Evolution Reaction via Programmable Metal Oxides
Hydrogen gas is a promising renewable energy storage medium when produced via water
electrolysis, but this process is limited by the sluggish kinetics of the anodic oxygen …
electrolysis, but this process is limited by the sluggish kinetics of the anodic oxygen …
Catalytic resonance theory: forecasting the flow of programmable catalytic loops
MA Murphy, K Noordhoek, SR Gathmann… - Digital …, 2025 - pubs.rsc.org
Chemical transformations on catalyst surfaces occur through series and parallel reaction
pathways. These complex networks and their behavior can be most simply evaluated …
pathways. These complex networks and their behavior can be most simply evaluated …
Endergonic synthesis driven by chemical fuelling
Spontaneous chemical reactions proceed energetically downhill to either a local or global
minimum, limiting possible transformations to those that are exergonic. Endergonic reactions …
minimum, limiting possible transformations to those that are exergonic. Endergonic reactions …