Helical polymers: synthesis, structures, and functions
The helix is the central structural motif in biological macromolecules, such as DNA and
proteins, and is also the ubiquitous object in nature from microscopic to macroscopic points …
proteins, and is also the ubiquitous object in nature from microscopic to macroscopic points …
Recent trends in chiroptical spectroscopy: theory and applications of vibrational circular dichroism and Raman optical activity
Chiroptical spectroscopy exploring the interaction of matter with polarized light provides
many tools for molecular structure and interaction studies. Here, some recent discoveries …
many tools for molecular structure and interaction studies. Here, some recent discoveries …
Chirality-responsive helical polymers
E Yashima, K Maeda - Macromolecules, 2008 - ACS Publications
Unique macromolecules that fold into a preferred-handed helical conformation induced by
external chiral stimuli are mainly described in this review. In contrast to small molecular …
external chiral stimuli are mainly described in this review. In contrast to small molecular …
Detection and amplification of chirality by helical polymers
E Yashima, K Maeda… - Chemistry–A European …, 2004 - Wiley Online Library
A unique feature of synthetic helical polymers for the detection and amplification of chirality
is briefly described in this article. In sharp contrast to host–guest and supramolecular …
is briefly described in this article. In sharp contrast to host–guest and supramolecular …
Dynamic helical structures: detection and amplification of chirality
K Maeda, E Yashima - Supramolecular chirality, 2006 - Springer
A unique feature of dynamic helical, chromophoric macromolecules that enables the
detection of a small imbalance in chiral guest molecules through a noncovalent bonding …
detection of a small imbalance in chiral guest molecules through a noncovalent bonding …
Conformational analysis of supramolecular polymerization processes of disc-like molecules
N, N′, N′′-Trialkylbenzene-1, 3, 5-tricarboxamides (BTAs) cooperatively self-assemble
into one-dimensional, helical supramolecular polymers in apolar alkane solutions. Previous …
into one-dimensional, helical supramolecular polymers in apolar alkane solutions. Previous …
Synthetic control of helical polyisocyanates by living anionic polymerization toward peptide mimicry
IG Bak, CG Chae, JS Lee - Macromolecules, 2022 - ACS Publications
We include 208 references with this Perspective to describe various helical polymers,
particularly polyisocyanates. Interest in polyisocyanates with helical properties is driven by …
particularly polyisocyanates. Interest in polyisocyanates with helical properties is driven by …
Hierarchical amplification of macromolecular helicity in a lyotropic liquid crystalline charged poly (phenylacetylene) by nonracemic dopants in water and its helical …
K Nagai, K Sakajiri, K Maeda, K Okoshi, T Sato… - …, 2006 - ACS Publications
We report a unique hierarchical amplification of chiral information from a nonracemic guest
to macromolecular helicity, followed by a mesoscopic, supramolecular cholesteric twist in …
to macromolecular helicity, followed by a mesoscopic, supramolecular cholesteric twist in …
Ternary polybenzoxazine/POSS/SWCNT hybrid nanocomposites stabilized through supramolecular interactions
In this study we linked zero-dimensional polyhedral oligomeric silsesquioxane (POSS) with
one-dimensional single-walled carbon nanotubes (SWCNTs) as dual-dimensional …
one-dimensional single-walled carbon nanotubes (SWCNTs) as dual-dimensional …
Helicity induction in a poly (phenylacetylene) bearing aza-18-crown-6 ether pendants with optically active bis (amino acid) s and its chiral stimuli-responsive gelation
K Morino, M Oobo, E Yashima - Macromolecules, 2005 - ACS Publications
A stereoregular poly (phenylacetylene) bearing the aza-18-crown-6 ether as the pendant
(poly-1) formed a predominantly one-handed helical conformation upon complexation with …
(poly-1) formed a predominantly one-handed helical conformation upon complexation with …