Mesoionic and related less heteroatom-stabilized N-heterocyclic carbene complexes: synthesis, catalysis, and other applications
Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …
Palladium-catalyzed Heck cross-coupling reactions in water: A comprehensive review
Palladium-catalyzed cross-coupling reactions have emerged as one of the most versatile
tools in organic chemistry. Extensive efforts were made to adapt these reactions to aqueous …
tools in organic chemistry. Extensive efforts were made to adapt these reactions to aqueous …
Metal‐Free Reduction of CO2 to Methoxyborane under Ambient Conditions through Borondiformate Formation
An abnormal N‐heterocyclic carbene (aNHC) based homogeneous catalyst has been used
for the reduction of carbon dioxide to methoxyborane in the presence of a range of …
for the reduction of carbon dioxide to methoxyborane in the presence of a range of …
A highly efficient base-metal catalyst: chemoselective reduction of imines to amines using an abnormal-NHC–Fe (0) complex
A base-metal, Fe (0)-catalyzed hydrosilylation of imines to obtain amines is reported here
which outperforms its noble-metal congeners with the highest TON of 17000. The catalyst,(a …
which outperforms its noble-metal congeners with the highest TON of 17000. The catalyst,(a …
An abnormal N-heterocyclic carbene based nickel complex for catalytic reduction of nitroarenes
Herein we report the synthesis of a nickel (II) dichloro complex bearing an abnormal N-
heterocyclic carbene (aNHC). The NiCl2 (aNHC) 2 complex has been used as an efficient …
heterocyclic carbene (aNHC). The NiCl2 (aNHC) 2 complex has been used as an efficient …
Cyclic (Alkyl) amino carbene based iron catalyst for regioselective dimerization of terminal arylalkynes
[(c AAC) Fe (CO) 4](1) catalyzed head-to-head dimerization of terminal arylalkynes toward
conjugated enynes in very high yield and high E selectivity (up to 84: 16 E: Z). The protocol …
conjugated enynes in very high yield and high E selectivity (up to 84: 16 E: Z). The protocol …
Abnormal-NHC-supported nickel catalysts for hydroheteroarylation of vinylarenes
Herein we report the hydroheteroarylation of vinylarenes with benzoxazole in the presence
of a free abnormal N-heterocyclic carbene and Ni (COD) 2, resulting in 1, 1-diarylethane …
of a free abnormal N-heterocyclic carbene and Ni (COD) 2, resulting in 1, 1-diarylethane …
Palladium-catalyzed oxidative Heck reaction of non-activated alkenes directed by fluorinated alcohol
B Zhu, Z Li, F Chen, W **ong, X Tan, M Lei… - Chemical …, 2022 - pubs.rsc.org
A novel, Pd-catalyzed oxidative Heck reaction of non-activated alkenes synergistically
directed by bifunctional groups has been developed firstly by using O2 as a green oxidant …
directed by bifunctional groups has been developed firstly by using O2 as a green oxidant …
One‐Pot Protocol for the Synthesis of Imidazoles and Quinoxalines using N‐Bromosuccinimide
Abstract N‐bromosuccinimide (NBS)‐mediated one‐pot, green, efficient and practical
synthesis of substituted imidazoles and quinoxalines has been achieved by the reaction of …
synthesis of substituted imidazoles and quinoxalines has been achieved by the reaction of …
C− I Selective Sonogashira and Heck Coupling Reactions Catalyzed by Aromatic Triangular Tri‐palladium
X Wang, L Sun, M Wang, G Maestri… - European Journal of …, 2022 - Wiley Online Library
Aromatic triangular tri‐palladium cations 1–3, abbreviated as [Pd3]+, have shown interesting
photoelectric properties, Lewis basic character, and excellent activities in catalytic …
photoelectric properties, Lewis basic character, and excellent activities in catalytic …