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Substitution reactions at boron atoms in metallacarboranes
VI Bregadze, SV Timofeev, IB Sivaev… - Russian chemical …, 2004 - iopscience.iop.org
Data on substitution reactions at boron atoms in 10–12-vertex metallacarboranes, which are
of fundamental and applied significance, are generalised. The possible mechanisms of …
of fundamental and applied significance, are generalised. The possible mechanisms of …
Mononuclear metallacarboranes of groups 6–10 metals: Analogues of metallocenes: Electrochemical and X-ray structural aspects
Metallacarboranes containing carborane ligands possessing a pentagonal open face can
coordinate metal atoms in a η5-manner quite similar to the cyclopentadienyl monoanion …
coordinate metal atoms in a η5-manner quite similar to the cyclopentadienyl monoanion …
Comparison of luminescent properties of helicene-like bibenzothiophenes with o-carborane and 5,6-dicarba-nido-decaborane
K Nishino, K Hashimoto, K Tanaka, Y Morisaki… - Science China …, 2018 - Springer
This article describes comparison of the anchoring effect on electronic properties of the
helicene-like bibenzothiophene between o-carborane and 5, 6-dicarba-nido-decaborane …
helicene-like bibenzothiophene between o-carborane and 5, 6-dicarba-nido-decaborane …
The first chiral HPLC separation of dicarba-nido-undecarborate anions and their chromatographic behavior
O Horáček, M Papajová-Janetková, B Grüner… - Talanta, 2021 - Elsevier
Boron cluster compounds are extensively studied due to their possible use in medicinal
chemistry, mainly in the boron neutron capture anticancer therapy and as new innovative …
chemistry, mainly in the boron neutron capture anticancer therapy and as new innovative …
Hypoelectronic metallaboranes: Synthesis, structural characterization and electronic structures of metal-rich cobaltaboranes
Abstract Reaction of [Cp∗ CoCl] 2 (Cp∗= η 5-C 5 Me 5) with [LiBH 4· THF] in toluene at− 70°
C, followed by thermolysis with 2-mercaptobenzothiazole (C 7 H 5 NS 2) in boiling toluene …
C, followed by thermolysis with 2-mercaptobenzothiazole (C 7 H 5 NS 2) in boiling toluene …
Emerging subject for chiral separation science: Cluster boron compounds
H Horakova, B Gruener, R Vespalec - Chirality, 2011 - Wiley Online Library
The structural chirality is an inherent feature of fully synthetic boron cluster compounds that
sometimes exhibit unique biochemical effects. HPLC studies with zwitter‐ionic cluster boron …
sometimes exhibit unique biochemical effects. HPLC studies with zwitter‐ionic cluster boron …
Experimental and theoretical study of the vibrational spectrum, structure and electron density distribution of the [2-CB10H11]− anion
EG Kononova, LA Leites, SS Bukalov, AV Zabula… - Chemical physics …, 2004 - Elsevier
The presence of two low-frequency large-amplitude modes in the vibrational spectrum,
experimental and computed data on B–B interatomic distances and the results of a …
experimental and computed data on B–B interatomic distances and the results of a …
Cluster rearrangement of isonido-ruthenacarboranes [1-(η6-1, 4-Me2C6H4)-3 (6)-Cl-isonido-1, 2, 4-RuC2B8H9] under thermal conditions
FM Dolgushin, AY Kostukovich, IV Pisareva… - Journal of …, 2014 - Elsevier
The heating of the isomeric [1-(η 6-1, 4-Me 2 C 6 H 4)-3-Cl-isonido-1, 2, 4-RuC 2 B 8 H 9](1)
or [1-(η 6-1, 4-Me 2 C 6 H 4)-6-Cl-isonido-1, 2, 4-RuC 2 B 8 H 9](2) complexes (i) in a 1, 4 …
or [1-(η 6-1, 4-Me 2 C 6 H 4)-6-Cl-isonido-1, 2, 4-RuC 2 B 8 H 9](2) complexes (i) in a 1, 4 …
Unexpected formation of clusters with a nortricyclene-containing carborane ligand, 1-(η 6-arene)-3-(C 7 H 9 CH 2 O)-isonido-1, 2, 4-RuC 2 B 8 H 9, in the reaction of 1 …
VE Konoplev, FM Dolgushin, IV Pisareva… - Russian chemical …, 2003 - Springer
Abstract Heating of 1, 1, 3-(PPh 3) 3-1-H-1, 2, 4-RuC 2 B 8 H 9 with 2-(hydroxymethyl)
bicyclo [2.2. 1] hepta-2, 5-diene in arene solvents (benzene, toluene, or mesitylene) …
bicyclo [2.2. 1] hepta-2, 5-diene in arene solvents (benzene, toluene, or mesitylene) …
New Iridathiaboranes with Reversible Isonido ↔ Nido Cluster Flexibility
The reaction between [IrCl (CO)(PMe3) 2] and the Cs [arachno-6-SB9H12] salt in CH2Cl2
yields pale-yellow 11-vertex [8, 8, 8-(CO)(PMe3) 2-nido-8, 7-IrSB9H10](4). Reaction of this …
yields pale-yellow 11-vertex [8, 8, 8-(CO)(PMe3) 2-nido-8, 7-IrSB9H10](4). Reaction of this …