The concept of active site in heterogeneous catalysis

C Vogt, BM Weckhuysen - Nature Reviews Chemistry, 2022 - nature.com
Catalysis is at the core of chemistry and has been essential to make all the goods
surrounding us, including fuels, coatings, plastics and other functional materials. In the near …

Control of metal-support interactions in heterogeneous catalysts to enhance activity and selectivity

TW van Deelen, C Hernández Mejía, KP de Jong - Nature Catalysis, 2019 - nature.com
Metal nanoparticles stabilized on a support material catalyse many major industrial
reactions. Metal-support interactions in these nanomaterials can have a substantial …

Selective hydrogenation over supported metal catalysts: from nanoparticles to single atoms

L Zhang, M Zhou, A Wang, T Zhang - Chemical reviews, 2019 - ACS Publications
Selective catalytic hydrogenation has wide applications in both petrochemical and fine
chemical industries, however, it remains challenging when two or multiple functional groups …

Well-defined materials for heterogeneous catalysis: from nanoparticles to isolated single-atom sites

Z Li, S Ji, Y Liu, X Cao, S Tian, Y Chen, Z Niu… - Chemical …, 2019 - ACS Publications
The use of well-defined materials in heterogeneous catalysis will open up numerous new
opportunities for the development of advanced catalysts to address the global challenges in …

Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …

W **g, H Shen, R Qin, Q Wu, K Liu, N Zheng - Chemical Reviews, 2022 - ACS Publications
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Surface coordination chemistry of atomically dispersed metal catalysts

R Qin, K Liu, Q Wu, N Zheng - Chemical Reviews, 2020 - ACS Publications
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …

Enhanced CO2 utilization in dry reforming of methane achieved through nickel-mediated hydrogen spillover in zeolite crystals

Q Zhu, H Zhou, L Wang, L Wang, C Wang, H Wang… - Nature Catalysis, 2022 - nature.com
Transformation of CO2 into precursors for chemicals and fuels by self-contained reducing
gas contaminants (for example, CH4) is attractive from a carbon economy perspective …

Gradient Hydrogen Migration Modulated with Self-Adapting S Vacancy in Copper-Doped ZnIn2S4 Nanosheet for Photocatalytic Hydrogen Evolution

S Zhang, Z Zhang, Y Si, B Li, F Deng, L Yang, X Liu… - ACS …, 2021 - ACS Publications
It is a challenge to regulate charge flow synergistically at the atomic level to modulate
gradient hydrogen migration (H migration) for boosting photocatalytic hydrogen evolution …

Solvent-free microwave synthesis of ultra-small Ru-Mo2C@CNT with strong metal-support interaction for industrial hydrogen evolution

X Wu, Z Wang, D Zhang, Y Qin, M Wang, Y Han… - Nature …, 2021 - nature.com
Exploring a simple, fast, solvent-free synthetic method for large-scale preparation of cheap,
highly active electrocatalysts for industrial hydrogen evolution reaction is one of the most …

Nurturing the marriages of single atoms with atomic clusters and nanoparticles for better heterogeneous electrocatalysis

L Zhang, J Zhu, X Li, S Mu, F Verpoort… - Interdisciplinary …, 2022 - Wiley Online Library
Single‐atom catalysts, featuring some of the most unique activities, selectivity, and high
metal utilization, have been extensively studied over the past decade. Given their high …