The concept of active site in heterogeneous catalysis

C Vogt, BM Weckhuysen - Nature Reviews Chemistry, 2022 - nature.com
Catalysis is at the core of chemistry and has been essential to make all the goods
surrounding us, including fuels, coatings, plastics and other functional materials. In the near …

Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …

W **g, H Shen, R Qin, Q Wu, K Liu, N Zheng - Chemical Reviews, 2022 - ACS Publications
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Unusual Sabatier principle on high entropy alloy catalysts for hydrogen evolution reactions

ZW Chen, J Li, P Ou, JE Huang, Z Wen… - Nature …, 2024 - nature.com
The Sabatier principle is widely explored in heterogeneous catalysis, graphically depicted in
volcano plots. The most desirable activity is located at the peak of the volcano, and further …

Weakened d–p orbital hybridization in in situ reconstructed Ru/β-Co (OH) 2 heterointerfaces for accelerated ammonia electrosynthesis from nitrates

W Zhu, F Yao, Q Wu, Q Jiang, J Wang… - Energy & …, 2023 - pubs.rsc.org
The electrocatalytic nitrate reduction reaction (NtrRR) has recently become an emerging
technology that can convert nitrate pollutants into high-value added ammonia products in a …

Enhanced CO2 utilization in dry reforming of methane achieved through nickel-mediated hydrogen spillover in zeolite crystals

Q Zhu, H Zhou, L Wang, L Wang, C Wang, H Wang… - Nature Catalysis, 2022 - nature.com
Transformation of CO2 into precursors for chemicals and fuels by self-contained reducing
gas contaminants (for example, CH4) is attractive from a carbon economy perspective …

Structured catalysts and catalytic processes: transport and reaction perspectives

C Pei, S Chen, D Fu, ZJ Zhao, J Gong - Chemical Reviews, 2024 - ACS Publications
The structure of catalysts determines the performance of catalytic processes. Intrinsically, the
electronic and geometric structures influence the interaction between active species and the …

MOFs-based materials for solid-state hydrogen storage: strategies and perspectives

Y Li, Q Guo, Z Ding, H Jiang, H Yang, W Du… - Chemical Engineering …, 2024 - Elsevier
Exceptionally porous crystals with ultrahigh adsorption capacities, metal–organic
frameworks (MOFs), have received recognition as leading candidates for the promotion of …

Heterolytic Dissociation of H2 in Heterogeneous Catalysis

DR Aireddy, K Ding - ACS Catalysis, 2022 - ACS Publications
H2 dissociation plays crucial roles in catalytic hydrogenation reactions and hydrogen
storage. Metal-nanoparticle-based heterogeneous catalysts often dissociate H2 via a …

Enhancement of Nitrate‐to‐Ammonia on Amorphous CeOx‐Modified Cu via Tuning of Active Hydrogen Supply

Y Li, C Wang, L Yang, W Ge, J Shen… - Advanced Energy …, 2024 - Wiley Online Library
The electrochemical nitrate reduction reaction (NO3RR) is an environment‐friendly and
promising alternative to the conventional Haber–Bosch ammonia synthesis process, which …

Gradient Hydrogen Migration Modulated with Self-Adapting S Vacancy in Copper-Doped ZnIn2S4 Nanosheet for Photocatalytic Hydrogen Evolution

S Zhang, Z Zhang, Y Si, B Li, F Deng, L Yang, X Liu… - ACS …, 2021 - ACS Publications
It is a challenge to regulate charge flow synergistically at the atomic level to modulate
gradient hydrogen migration (H migration) for boosting photocatalytic hydrogen evolution …