Phosphorus-based Mannich-type reactions (phospha-Mannich reactions) of primary or
secondary phosphines with carbonyl compounds and amines (R2NH, RNH2, and NH3) …

This chapter covers the literature published during 2013 relating to the above area, apart
from a few papers from 2012 in less accessible journals which came to light in Chemical …

This review article provides the reader with numerous evidence that 3a, 6a-diaza-1, 4-
diphosphapentalenes are a form of existence of stabilized singlet phosphinidenes. In …

Abstract 3a, 6a-Diaza-1, 4-diphosphapentalene (DDP) with indium triiodide forms the [In
(DDP) I 3] complex (I) with the ratio In: DDP= 1: 1. The DDP ligand reacts with antimony (III) …

Dialkyl-1, 3-benzazaphospholine-2-carboxylic acids 2a, b can be conveniently prepared by
metalation and alkylation of N-methyl-and N-neopentyl-o-phosphanylaniline in liquid …

This account reviews recent syntheses, properties, and the reactivity of electron‐rich
aromatic 1, 3‐heterophospholes, with the focus on benzazaphospholes, but also with …

The influence of solvents on the lithiation of N-methyl-1, 3-benzazaphospholes is reported;
these are accessible via catalytic phosphonylation of 2-bromoanilines, subsequent …

Attempts to prepare mixed M (0)/Ag+ complexes with µ‐bridging P ligands by reaction of
benzazaphosphole M (CO) 5 complexes 1a–e (M W, Mo, Cr) with AgSbF6 in THF lead to …

Developments in the chemistry of five-membered ring heterocycles containing two non-
adjacent heteroatoms, with at least one phosphorus, in the period 2008–2020 are reviewed …

Coordination chemical studies of 1H-1, 3-benzazaphospholes, π-excess aromatic σ2P-
ligands, demonstrate similar ligand properties to those of phosphabenzenes toward MVI …