Integration or segregation: how do molecules behave at oil/water interfaces?

FG Moore, GL Richmond - Accounts of chemical research, 2008 - ACS Publications
It has been over 250 years since Benjamin Franklin, fascinated with the wave-stilling effect
of oil on water, performed his famous oil-drop experiments; nevertheless, the behavior of …

Theoretical studies of structures and vibrational sum frequency generation spectra at aqueous interfaces

T Ishiyama, T Imamura, A Morita - Chemical reviews, 2014 - ACS Publications
Aqueous interfaces, including water, ice, and electrolyte solutions, are ubiquitous and play
crucial roles in diverse fields of chemistry. Such interfaces are relevant to electrodes in …

Effects of surface functional groups on electron transfer at liquid–solid interfacial contact electrification

S Lin, M Zheng, J Luo, ZL Wang - ACS nano, 2020 - ACS Publications
Contact electrification (CE) at interfaces is sensitive to the functional groups on the solid
surface, but its mechanism is poorly understood, especially for the liquid–solid cases. A core …

Structure and charging of hydrophobic material/water interfaces studied by phase-sensitive sum-frequency vibrational spectroscopy

CS Tian, YR Shen - … of the National Academy of Sciences, 2009 - National Acad Sciences
We have studied the hydrophobic water/octadecyltrichlorosilane (OTS) interface by using
the phase-sensitive sum-frequency vibrational spectroscopy (PS-SFVS), and we obtained …

A new method for determining the interfacial molecules and characterizing the surface roughness in computer simulations. Application to the liquid–vapor interface of …

LB Pártay, G Hantal, P Jedlovszky… - Journal of …, 2008 - Wiley Online Library
A new method is presented to identify the truly interfacial molecules at fluid/fluid interfaces
seen at molecular resolution, a situation that regularly occurs in computer simulations. In the …

Interfacial tension-impelled self-assembly and morphology tuning of poly (3, 4-ethylene dioxythiophene)/tellurium nanocomposites at various liquid/liquid interfaces

N Puthiyottil, A Palamparambil… - … Applied Materials & …, 2023 - ACS Publications
Compared to the enormous number of nanostructures that have been documented, the
variety of nanostructures produced by organic polymerization is rather limited. We devised …

Variation of ionic strength reveals the interfacial water structure at a charged mineral surface

KC Jena, DK Hore - The Journal of Physical Chemistry C, 2009 - ACS Publications
We have used visible-infrared sum-frequency generation spectroscopy to study the structure
of water molecules that form the interface with fused silica. Spectra throughout the OH …

Formation and surface-stabilizing contributions to bare nanoemulsions created with negligible surface charge

AP Carpenter, E Tran, RM Altman… - Proceedings of the …, 2019 - National Acad Sciences
The stabilization of nanoemulsions, nanosized oil droplets dispersed in water, is commonly
achieved through the addition of surfactants and polymers. However, nanoemulsions in the …

Ordered polyelectrolyte assembly at the oil–water interface

DK Beaman, EJ Robertson… - Proceedings of the …, 2012 - National Acad Sciences
Polyelectrolytes (PEs) are widely used in applications such as water purification, wastewater
treatment, and mineral recovery. Although much has been learned in past decades about …

Temperature dependence of dimerization and dewetting of large-scale hydrophobes: a molecular dynamics study

R Zangi, BJ Berne - The Journal of Physical Chemistry B, 2008 - ACS Publications
We studied by molecular dynamics simulations the temperature dependence of hydrophobic
association and drying transition of large-scale solutes. Similar to the behavior of small …