Recent progress on cyano-bridged transition-metal-based single-molecule magnets and single-chain magnets

JH Wang, ZY Li, M Yamashita, XH Bu - Coordination Chemistry Reviews, 2021 - Elsevier
Novel functional molecular-based magnetic materials, especially some members of the
Prussian blue family, have gained significant attention over the past few decades as they …

Tricyanometalate molecular chemistry: A type of versatile building blocks for the construction of cyano-bridged molecular architectures

S Wang, XH Ding, JL Zuo, XZ You, W Huang - Coordination chemistry …, 2011 - Elsevier
Cyano-bridged molecule-based magnetic materials with reduced dimensionality, such as
single-molecule magnets (SMMs) and single-chain magnets (SCMs), have attracted great …

Single-molecule magnet engineering: building-block approaches

KS Pedersen, J Bendix, R Clérac - Chemical Communications, 2014 - pubs.rsc.org
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

Magnetic and optical bistability driven by thermally and photoinduced intramolecular electron transfer in a molecular cobalt− iron Prussian blue analogue

D Li, R Clérac, O Roubeau, E Harté… - Journal of the …, 2008 - ACS Publications
A soluble molecular analogue of photoresponsive Co/Fe Prussian blues is described within
this report. As judged via a variety of spectroscopic, magnetic, and crystallographic methods …

Slow dynamics of the magnetization in one-dimensional coordination polymers: single-chain magnets

H Miyasaka, M Julve, M Yamashita… - Inorganic chemistry, 2009 - ACS Publications
Slow relaxation of the magnetization (ie,“magnet-like” behavior) in materials composed of
magnetically isolated chains was observed for the first time in 2001. This type of behavior …

An organometallic sandwich lanthanide single-ion magnet with an unusual multiple relaxation mechanism

M Jeletic, PH Lin, JJ Le Roy, I Korobkov… - Journal of the …, 2011 - ACS Publications
A dysprosium (III) sandwich complex,[DyIII (COT ″) 2Li (THF)(DME)], was synthesized using
1, 4-bis (trimethylsilyl) cyclooctatetraenyl dianion (COT ″). The complex behaves as a …

Controlled intramolecular electron transfers in cyanide-bridged molecular squares by chemical modifications and external stimuli

M Nihei, Y Sekine, N Suganami… - Journal of the …, 2011 - ACS Publications
A series of cyanide bridged Fe− Co molecular squares,[Co2Fe2 (CN) 6 (tp*) 2 (dtbbpy)
4](PF6) 2· 2MeOH (1),[Co2Fe2 (CN) 6 (tp*) 2 (bpy) 4](PF6) 2· 2MeOH (2), and [Co2Fe2 (CN) …

Importance of Out-of-State Spin–Orbit Coupling for Slow Magnetic Relaxation in Mononuclear FeII Complexes

PH Lin, NC Smythe, SI Gorelsky… - Journal of the …, 2011 - ACS Publications
Two mononuclear high-spin FeII complexes with trigonal planar ([FeII (N (TMS) 2) 2
(PCy3)](1) and distorted tetrahedral ([FeII (N (TMS) 2) 2 (depe)](2) geometries are reported …

Trigonal antiprismatic Co (II) single molecule magnets with large uniaxial anisotropies: importance of Raman and tunneling mechanisms

YZ Zhang, S Gómez-Coca, AJ Brown, MR Saber… - Chemical …, 2016 - pubs.rsc.org
The air-stable mononuclear Co (II) compounds [CoII (Tpm) 2][ClO4] 2 (1, Tpm= tris (pyrazol-
1-yl) methane),[CoII (Tpm) 2][BPh4] 2· 2MeCN (2) with trigonal antiprismatic geometry …

Trinuclear Heterobimetallic Ni2Ln complexes [L2Ni2Ln][ClO4](Ln= La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, and Er; LH3=(S) P [N (Me) N CH− C6H3-2-OH-3-OMe] 3) …

V Chandrasekhar, BM Pandian… - Inorganic …, 2008 - ACS Publications
The reaction of LH3 with Ni (ClO4) 2· 6H2O and lanthanide salts in a 2: 2: 1 ratio in the
presence of triethylamine leads to the formation of the trinuclear complexes …