Catalytic Upcycling of Polyolefins

J Sun, J Dong, L Gao, YQ Zhao, H Moon… - Chemical …, 2024 - ACS Publications
The large production volumes of commodity polyolefins (specifically, polyethylene,
polypropylene, polystyrene, and poly (vinyl chloride)), in conjunction with their low unit …

Precise activation of C–C bonds for recycling and upcycling of plastics

H Ran, S Zhang, W Ni, Y **g - Chemical Science, 2024 - pubs.rsc.org
The rapid accumulation of plastic waste has led to a severe environmental crisis and a
noticeable imbalance between manufacturing and recycling. Fortunately, chemical …

Polystyrene Hydrogenolysis to High-Quality Lubricants Using Ni/SiO2

BC Vance, S Najmi, DG Vlachos - ACS Catalysis, 2024 - ACS Publications
Pyrolytic and light-activated oxidation processes are leading technologies for utilizing
polystyrene (PS) wastes. These approaches exhibit poor selectivities, use complex reactors …

Review on catalytic depolymerization of polyolefin waste by hydrogenolysis: state-of-the-art and outlook

A Musa, EA Jaseer, S Barman, N Garcia - Energy & Fuels, 2024 - ACS Publications
Mechanical recycling of plastic waste is not sustainable and inefficient in terms of the
resources needed to accomplish the process, and the quality of the materials obtained from …

Highly Selective and Efficient Perdeuteration of n‐Pentane via H/D Exchange Catalyzed by a Silica‐Supported Hafnium‐Iridium Bimetallic Complex

AV Pichugov, L Escomel, S Lassalle… - Angewandte Chemie …, 2024 - Wiley Online Library
Abstract A Surface OrganoMetallic Chemistry (SOMC) approach is used to prepare a novel
hafnium‐iridium catalyst immobilized on silica, HfIr/SiO2, featuring well‐defined [≡ SiOHf …

Tandem Methanolysis and Catalytic Transfer Hydrogenolysis of Polyethylene Terephthalate to p‐Xylene Over Cu/ZnZrOx Catalysts

R Helmer, SS Borkar, A Li, F Mahnaz… - Angewandte Chemie …, 2025 - Wiley Online Library
We demonstrate a novel approach of utilizing methanol (CH3OH) in a dual role for (1) the
methanolysis of polyethylene terephthalate (PET) to form dimethyl terephthalate (DMT) at …

Quantifying synergy for mixed end-scission and random-scission catalysts in polymer upcycling

Z Chen, E Ejiogu, B Peters - Reaction Chemistry & Engineering, 2024 - pubs.rsc.org
The environmental consequences of plastic waste are driving research into many chemical
and catalytic recycling strategies. The isomerizing ethenolysis strategy for polyethylene …

Catalytic Strategies for the Upcycling of Polyolefin Plastic Waste

S Xu, J Tang, L Fu - Langmuir, 2024 - ACS Publications
Chemical upgrading of waste plastics is currently one of the most important methods for
addressing plastic pollution. In comparison to the current methods of incineration or landfill …

Converting waste plastic to liquid organic hydrogen carriers

M Soltani, JE Rorrer - Angewandte Chemie International …, 2023 - Wiley Online Library
The accumulation of waste plastics in landfills and the environment, as well as the
contribution of plastics manufacturing to global warming, call for the development of new …

Hydrogenolysis of Polyethylene by Metal–Organic Framework Confined Single-Site Ruthenium Catalysts

M Chauhan, C Thadhani, B Rana, P Gupta… - Chemistry of …, 2024 - ACS Publications
Upcycling polyolefins into value-added hydrocarbons via catalytic hydrogenolysis is
challenging due to poor product selectivity, random C–C bond cleavage, and the formation …