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Electrochemical methods for water purification, ion separations, and energy conversion
Agricultural development, extensive industrialization, and rapid growth of the global
population have inadvertently been accompanied by environmental pollution. Water …
population have inadvertently been accompanied by environmental pollution. Water …
Graphite as anode materials: Fundamental mechanism, recent progress and advances
Graphite is a perfect anode and has dominated the anode materials since the birth of lithium
ion batteries, benefiting from its incomparable balance of relatively low cost, abundance …
ion batteries, benefiting from its incomparable balance of relatively low cost, abundance …
Multiscale dynamics of charging and plating in graphite electrodes coupling operando microscopy and phase-field modelling
The phase separation dynamics in graphitic anodes significantly affects lithium plating
propensity, which is the major degradation mechanism that impairs the safety and fast …
propensity, which is the major degradation mechanism that impairs the safety and fast …
Intercalation chemistry of graphite: alkali metal ions and beyond
Reversibly intercalating ions into host materials for electrochemical energy storage is the
essence of the working principle of rocking-chair type batteries. The most relevant example …
essence of the working principle of rocking-chair type batteries. The most relevant example …
Theory-guided experimental design in battery materials research
A reliable energy storage ecosystem is imperative for a renewable energy future, and
continued research is needed to develop promising rechargeable battery chemistries. To …
continued research is needed to develop promising rechargeable battery chemistries. To …
Interplay of lithium intercalation and plating on a single graphite particle
Improving safety while increasing the charging rates and extending the lifetime is the grand
challenge for lithium-ion batteries. The key challenge is to control lithium plating, a parasitic …
challenge for lithium-ion batteries. The key challenge is to control lithium plating, a parasitic …
Spatial dynamics of lithiation and lithium plating during high-rate operation of graphite electrodes
The principal inhibitor of fast charging lithium ion cells is the graphite negative electrode,
where favorable conditions for lithium plating occur at high charge rates, causing …
where favorable conditions for lithium plating occur at high charge rates, causing …
Editors' choice—review—impedance response of porous electrodes: theoretical framework, physical models and applications
Porous electrodes are prevalent in electrochemical devices. Electrochemical impedance
spectroscopy (EIS) is widely used as a noninvasive, in situ characterization tool to …
spectroscopy (EIS) is widely used as a noninvasive, in situ characterization tool to …
Strategies for the analysis of graphite electrode function
Since the commercialization of lithium‐ion batteries, graphite has been the uncontested
material of choice as the negative electrode host structure, and it has therefore been pivotal …
material of choice as the negative electrode host structure, and it has therefore been pivotal …
Unified quantum theory of electrochemical kinetics by coupled ion–electron transfer
MZ Bazant - Faraday Discussions, 2023 - pubs.rsc.org
A general theory of coupled ion–electron transfer (CIET) is presented, which unifies Marcus
kinetics of electron transfer (ET) with Butler–Volmer kinetics of ion transfer (IT). In the limit of …
kinetics of electron transfer (ET) with Butler–Volmer kinetics of ion transfer (IT). In the limit of …